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Cited by 284

The DOI matches its Crossref record; 38 of the 38 references it cites were found in a registry or an index.

Porous Organic Cages for Sulfur Hexafluoride Separation

Open access
Hasell, Tom, Miklitz, Marcin, Stephenson, Andrew, Little, Marc A., Chong, Samantha Y., Clowes, Rob, Chen, Linjiang, Holden, Daniel, Tribello, Gareth A., Jelfs, Kim E., Cooper, Andrew I.·2016·Journal of the American Chemical Society

Abstract

A series of porous organic cages is examined for the selective adsorption of sulfur hexafluoride (SF6) over nitrogen. Despite lacking any metal sites, a porous cage, CC3, shows the highest SF6/N2 selectivity reported for any material at ambient temperature and pressure, which translates to real separations in a gas breakthrough column. The SF6 uptake of these materials is considerably higher than would be expected from the static pore structures. The location of SF6 within these materials is elucidated by X-ray crystallography, and it is shown that cooperative diffusion and structural rearrangements in these molecular crystals can rationalize their superior SF6/N2 selectivity.

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Crossref · 10.1021/jacs.5b11797

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Metadata

Authors
Hasell, T., Miklitz, M., Stephenson, A., Little, M. A., Chong, S. Y., Clowes, R., Chen, L., Holden, D., Tribello, G. A., Jelfs, K. E., & Cooper, A. I.
Venue
Journal of the American Chemical Society
Published
2016-01-27
Volume
138
Issue
5
Pages
1653-1659
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2234843652
Cited by
284
References
38
FWCI
13.24
Type
journal article
Language
en
Open access
hybrid

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CoChat. (2026). Citation check: Porous Organic Cages for Sulfur Hexafluoride Separation. https://app.cochat.ai/papers/10.1021/jacs.5b11797
The paper
Hasell, T., Miklitz, M., Stephenson, A., Little, M. A., Chong, S. Y., Clowes, R., Chen, L., Holden, D., Tribello, G. A., Jelfs, K. E., & Cooper, A. I. (2016). Porous Organic Cages for Sulfur Hexafluoride Separation. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b11797

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