The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Beyond Dispersity: Deterministic Control of Polymer Molecular Weight Distribution
Abstract
The breadth of the molecular weight distributions (MWD) of polymers influences their physical properties; however, no synthetic methods allow precise control of the exact shape and composition of a distribution. We report a modular strategy that enables deterministic control over polymer MWD through temporal regulation of initiation in nitroxide-mediated polymerization reactions. This approach is applicable to any controlled polymerization that uses a discrete initiator, and it allows the use of MWD composition as a parameter to tune material properties.
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Citations
Cites
Polydispersity and block copolymer self-assembly
Lynd, N. A., Meuler, A. J., & Hillmyer, M. A. (2008) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2008.07.003 · Cited by 485
Influence of Polydispersity on the Self-Assembly of Diblock Copolymers
Lynd, N. A., & Hillmyer, M. A. (2005) · Macromolecules · doi:10.1021/ma051025r · Cited by 309
Benoit, D., Harth, E., Fox, P., Waymouth, R. M., & Hawker, C. J. (2000) · Macromolecules · doi:10.1021/ma991187l · Cited by 216
Cited by
Recent Developments and Future Challenges in Controlled Radical Polymerization: A 2020 Update
Parkatzidis, K., Wang, H. S., Truong, N. P., & Anastasaki, A. (2020) · Chem · doi:10.1016/j.chempr.2020.06.014 · Cited by 512
50th Anniversary Perspective: Living Polymerization—Emphasizing the Molecule in Macromolecules
Grubbs, R. B., & Grubbs, R. H. (2017) · Macromolecules · doi:10.1021/acs.macromol.7b01440 · Cited by 396
Ultra-High Molecular Weights via Aqueous Reversible-Deactivation Radical Polymerization
Carmean, R. N., Becker, T. E., Sims, M. B., & Sumerlin, B. S. (2017) · Chem · doi:10.1016/j.chempr.2016.12.007 · Cited by 292
Recent progress on polydispersity effects on block copolymer phase behavior
Kim, I., & Li, S. (2019) · Polymer Reviews · doi:10.1080/15583724.2019.1579227 · Cited by 30
Augmenting Polymer Datasets by Iterative Rearrangement
(2023) · doi:10.1021/acs.jcim.3c00144 · Cited by 19
Metadata
- Authors
- Gentekos, D. T., Dupuis, L. N., & Fors, B. P.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-02-02
- Volume
- 138
- Issue
- 6
- Pages
- 1848-1851
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2258866110
- Cited by
- 170
- References
- 3
- FWCI
- 9.35
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gentekos, D. T., Dupuis, L. N., & Fors, B. P. (2016). Beyond Dispersity: Deterministic Control of Polymer Molecular Weight Distribution. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b13565
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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