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Ultrafine NiO Nanosheets Stabilized by TiO2 from Monolayer NiTi-LDH Precursors: An Active Water Oxidation Electrocatalyst

Zhao, Yufei, Jia, Xiaodan, Chen, Guangbo, Shang, Lu, Waterhouse, Geoffrey I.N., Wu, Li-Zhu, Tung, Chen-Ho, O’Hare, Dermot, Zhang, Tierui·2016·Journal of the American Chemical Society

Abstract

Faceted NiO nanoparticles preferentially exposing high surface energy planes demand attention due to their excellent electrocatalytic properties. However, the activity of faceted NiO nanoparticles generally remains suboptimal due to their large lateral size and thickness, which severely limits the availability of coordinatively unsaturated active reactive edge and corner sites. Here, ultrafine NiO nanosheets with a platelet size of ∼4.0 nm and thickness (∼1.1 nm) stabilized by TiO2 were successfully prepared by calcination of a monolayer layered double hydroxide precursor. The ultrafine NiO nanosheets displayed outstanding performance in electrochemical water oxidation due to a high proportion of reactive NiO {110} facets, intrinsic Ni(3+) and Ti(3+) sites, and abundant interfaces, which act synergistically to promote H2O adsorption and facilitate charge-transfer.

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Metadata

Authors
Zhao, Y., Jia, X., Chen, G., Shang, L., Waterhouse, G. I. N., Wu, L.-Z., Tung, C.-H., O’Hare, D., & Zhang, T.
Venue
Journal of the American Chemical Society
Published
2016-05-16
Volume
138
Issue
20
Pages
6517-6524
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2345936754
Cited by
730
References
3
FWCI
22.35
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Ultrafine NiO Nanosheets Stabilized by TiO2 from Monolayer NiTi-LDH Precursors: An Active Water Oxidation Electrocatalyst. https://app.cochat.ai/papers/10.1021/jacs.6b01606
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Zhao, Y., Jia, X., Chen, G., Shang, L., Waterhouse, G. I. N., Wu, L.-Z., Tung, C.-H., O’Hare, D., & Zhang, T. (2016). Ultrafine NiO Nanosheets Stabilized by TiO2 from Monolayer NiTi-LDH Precursors: An Active Water Oxidation Electrocatalyst. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.6b01606

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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.