The DOI matches its Crossref record; 64 of the 64 references it cites were found in a registry or an index.
Catalytically Active Bimetallic Nanoparticles Supported on Porous Carbon Capsules Derived From Metal–Organic Framework Composites
Abstract
We report a new methodology for producing monometallic or bimetallic nanoparticles confined within hollow nitrogen-doped porous carbon capsules. The capsules are derived from metal-organic framework (MOF) crystals that are coated with a shell of a secondary material comprising either a metal-tannic acid coordination polymer or a resorcinol-formaldehyde polymer. Platinum nanoparticles are optionally sandwiched between the MOF core and the shell. Pyrolysis of the MOF-shell composites produces hollow capsules of porous nitrogen-doped carbon that bear either monometallic (Pt, Co, and Ni) or alloyed (PtCo and PtNi) metal nanoparticles. The Co and Ni components of the bimetallic nanoparticles are derived from the shell surrounding the MOF crystals. The hollow capsules prevent sintering and detachment of the nanoparticles, and their porous walls allow for efficient mass transport. Alloyed PtCo nanoparticles embedded in the capsule walls are highly active, selective, and recyclable catalysts for the hydrogenation of nitroarenes to anilines.
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High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO 2 Capture
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Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces
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Recent Progress in the Synthesis of Porous Carbon Materials
Lee, J., Kim, J., & Hyeon, T. (2006) · Advanced Materials · doi:10.1002/adma.200501576 · Cited by 2,127
Mesoporous carbon materials: Synthesis and modification
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A facile soft-template synthesis of mesoporous polymeric and carbonaceous nanospheres
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Encapsulated Metal Nanoparticles for Catalysis
Gao, C., Lyu, F., & Yin, Y. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00237 · Cited by 855
Liu, M., Wang, L., Zhao, K., Shi, S., Shao, Q., Zhang, L., Sun, X., Zhao, Y., & Zhang, J. (2019) · Energy & Environmental Science · doi:10.1039/c9ee01722d · Cited by 429
Nanoengineering Carbon Spheres as Nanoreactors for Sustainable Energy Applications
Tian, H., Liang, J., & Liu, J. (2019) · Advanced Materials · doi:10.1002/adma.201903886 · Cited by 348
Metadata
- Authors
- Yang, H., Bradley, S. J., Chan, A., Waterhouse, G. I. N., Nann, T., Kruger, P. E., & Telfer, S. G.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-08-30
- Volume
- 138
- Issue
- 36
- Pages
- 11872-11881
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2511586762
- Cited by
- 284
- References
- 64
- FWCI
- 15.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yang, H., Bradley, S. J., Chan, A., Waterhouse, G. I. N., Nann, T., Kruger, P. E., & Telfer, S. G. (2016). Catalytically Active Bimetallic Nanoparticles Supported on Porous Carbon Capsules Derived From Metal–Organic Framework Composites. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.6b06736
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