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Cited by 284

The DOI matches its Crossref record; 64 of the 64 references it cites were found in a registry or an index.

Catalytically Active Bimetallic Nanoparticles Supported on Porous Carbon Capsules Derived From Metal–Organic Framework Composites

Yang, Hui, Bradley, Siobhan J., Chan, Andrew, Waterhouse, Geoffrey I. N., Nann, Thomas, Kruger, Paul E., Telfer, Shane G.·2016·Journal of the American Chemical Society

Abstract

We report a new methodology for producing monometallic or bimetallic nanoparticles confined within hollow nitrogen-doped porous carbon capsules. The capsules are derived from metal-organic framework (MOF) crystals that are coated with a shell of a secondary material comprising either a metal-tannic acid coordination polymer or a resorcinol-formaldehyde polymer. Platinum nanoparticles are optionally sandwiched between the MOF core and the shell. Pyrolysis of the MOF-shell composites produces hollow capsules of porous nitrogen-doped carbon that bear either monometallic (Pt, Co, and Ni) or alloyed (PtCo and PtNi) metal nanoparticles. The Co and Ni components of the bimetallic nanoparticles are derived from the shell surrounding the MOF crystals. The hollow capsules prevent sintering and detachment of the nanoparticles, and their porous walls allow for efficient mass transport. Alloyed PtCo nanoparticles embedded in the capsule walls are highly active, selective, and recyclable catalysts for the hydrogenation of nitroarenes to anilines.

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Metadata

Authors
Yang, H., Bradley, S. J., Chan, A., Waterhouse, G. I. N., Nann, T., Kruger, P. E., & Telfer, S. G.
Venue
Journal of the American Chemical Society
Published
2016-08-30
Volume
138
Issue
36
Pages
11872-11881
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2511586762
Cited by
284
References
64
FWCI
15.00
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Catalytically Active Bimetallic Nanoparticles Supported on Porous Carbon Capsules Derived From Metal–Organic Framework Composites. https://app.cochat.ai/papers/10.1021/jacs.6b06736
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Yang, H., Bradley, S. J., Chan, A., Waterhouse, G. I. N., Nann, T., Kruger, P. E., & Telfer, S. G. (2016). Catalytically Active Bimetallic Nanoparticles Supported on Porous Carbon Capsules Derived From Metal–Organic Framework Composites. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.6b06736

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