The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
The Fixed Propeller-Like Conformation of Tetraphenylethylene that Reveals Aggregation-Induced Emission Effect, Chiral Recognition, and Enhanced Chiroptical Property
Abstract
The propeller-like conformation of tetraphenylethylene (TPE) with aggregation-induced emission (AIE) effect was partially and completely fixed by intramolecular cyclization for the first time. The immobilization of propeller-like conformation was found to show great advantages in determining the enantiomer purity, identifying the chiral amines. The completely fixed conformers are resolved into M- and P-enantiomer, which showed mirror imaged CD and almost quantitative fluorescence quantum yield. Furthermore, it also showed a mirror and large circularly polarized luminescence dissymmetric factor, depending on the helicity of the enantiomer. The result provides the most direct and persuasive evidence for AIE via the restriction of intramolecular rotation and finds the new insight of the compounds in chiroptical property.
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Cites
Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole
Luo, J., Xie, Z., Lam, J. W. Y., Cheng, L., Tang, B. Z., Chen, H., Qiu, C., Kwok, H. S., Zhan, X., Liu, Y., et al. (2001) · Chemical Communications · doi:10.1039/b105159h · Cited by 8,358
Aggregation-Induced Emission: Together We Shine, United We Soar!
Mei, J., Leung, N. L. C., Kwok, R. T. K., Lam, J. W. Y., & Tang, B. Z. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00263 · Cited by 8,270
Cited by
Gong, Z.-L., Zhu, X., Zhou, Z., Zhang, S.-W., Yang, D., Zhao, B., Zhang, Y.-P., Deng, J., Cheng, Y., Zheng, Y.-X., et al. (2021) · Science China Chemistry · doi:10.1007/s11426-021-1146-6 · Cited by 608
Self-citationAggregate Science: From Structures to Properties
Zhang, H., Zhao, Z., Turley, A. T., Wang, L., McGonigal, P. R., Tu, Y., Li, Y., Wang, Z., Kwok, R. T. K., Lam, J. W. Y., et al. (2020) · Advanced Materials · doi:10.1002/adma.202001457 · Cited by 518
Cooperative Chirality and Sequential Energy Transfer in a Supramolecular Light‐Harvesting Nanotube
Ji, L., Sang, Y., Ouyang, G., Yang, D., Duan, P., Jiang, Y., & Liu, M. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201812642 · Cited by 284
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Metadata
- Authors
- Xiong, J.-B., Feng, H.-T., Sun, J.-P., Xie, W.-Z., Yang, D., Liu, M., & Zheng, Y.-S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-08-30
- Volume
- 138
- Issue
- 36
- Pages
- 11469-11472
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2513121041
- Cited by
- 286
- References
- 2
- FWCI
- 11.64
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xiong, J.-B., Feng, H.-T., Sun, J.-P., Xie, W.-Z., Yang, D., Liu, M., & Zheng, Y.-S. (2016). The Fixed Propeller-Like Conformation of Tetraphenylethylene that Reveals Aggregation-Induced Emission Effect, Chiral Recognition, and Enhanced Chiroptical Property. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.6b07087
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