The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Ultrafine Pt Nanoclusters Confined in a Calixarene-Based {Ni24} Coordination Cage for High-Efficient Hydrogen Evolution Reaction
Abstract
To obtain stable and ultrafine Pt nanoclusters, a trigonal prismatic coordination cage with the sulfur atoms on the edges was solvothermally synthesized to confine them. In the structure of {Ni 24 (TC4A-SO 2 ) 6 (TDC) 12 (H 2 O) 6 } (H 4 TC4A-SO 2 = p-tert -butylsulfonylcalix[4]arene; H 2 TDC = 2,5-thiophenedicarboxylic acid), three Ni 4 -(TC4A-SO 2 ) SBUs are bridged by three TDC ligands into a triangle and two such triangles are pillared by three pairs of TDC ligands to form a trigonal prism. The cage cavity has 12 sulfur atoms on the surface. Because of the porous structure and strong covalent interaction between metal and sulfur, ultrafine Pt nanoclusters composed of less than ∼18 Pt atoms can be facilely confined in the present trigonal prismatic cage ( Pt@CIAC-121 ). The as-synthesized Pt NCs exhibit higher electrocatalytic activity than commercial Pt/C toward hydrogen evolution reaction.
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Cites
MoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Popczun, E. J., Read, C. G., Roske, C. W., Lewis, N. S., & Schaak, R. E. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402646 · Cited by 1,240
Cao, B., Veith, G. M., Neuefeind, J. C., Adzic, R. R., & Khalifah, P. G. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4081056 · Cited by 998
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High activity PtPd-WC/C electrocatalyst for hydrogen evolution reaction
Wu, M., Shen, P. K., Wei, Z., Song, S., & Nie, M. (2007) · Journal of Power Sources · doi:10.1016/j.jpowsour.2006.12.108 · Cited by 118
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Li, W., Liu, Y., Wu, M., Feng, X., Redfern, S. A. T., Shang, Y., Yong, X., Feng, T., Wu, K., Liu, Z., et al. (2018) · Advanced Materials · doi:10.1002/adma.201800676 · Cited by 642
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Metadata
- Authors
- Wang, S., Gao, X., Hang, X., Zhu, X., Han, H., Liao, W., & Chen, W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-12-09
- Volume
- 138
- Issue
- 50
- Pages
- 16236-16239
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2560209319
- Cited by
- 202
- References
- 6
- FWCI
- 5.81
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, S., Gao, X., Hang, X., Zhu, X., Han, H., Liao, W., & Chen, W. (2016). Ultrafine Pt Nanoclusters Confined in a Calixarene-Based {Ni24} Coordination Cage for High-Efficient Hydrogen Evolution Reaction. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.6b11218
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