The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Isolated Single-Atom Pd Sites in Intermetallic Nanostructures: High Catalytic Selectivity for Semihydrogenation of Alkynes
Abstract
Improving the catalytic selectivity of Pd catalysts is of key importance for various industrial processes and remains a challenge so far. Given the unique properties of single-atom catalysts, isolating contiguous Pd atoms into a single-Pd site with another metal to form intermetallic structures is an effective way to endow Pd with high catalytic selectivity and to stabilize the single site with the intermetallic structures. Based on density functional theory modeling, we demonstrate that the (110) surface of Pm 3̅ m PdIn with single-atom Pd sites shows high selectivity for semihydrogenation of acetylene, whereas the (111) surface of P 4/ mmm Pd 3 In with Pd trimer sites shows low selectivity. This idea has been further validated by experimental results that intermetallic PdIn nanocrystals mainly exposing the (110) surface exhibit much higher selectivity for acetylene hydrogenation than Pd 3 In nanocrystals mainly exposing the (111) surface (92% vs 21% ethylene selectivity at 90 °C). This work provides insight for rational design of bimetallic metal catalysts with specific catalytic properties.
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Cites
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
From ultrasoft pseudopotentials to the projector augmented-wave method
Kresse, G., & Joubert, D. (1999) · Physical Review B · doi:10.1103/physrevb.59.1758 · Cited by 85,307
Kim, D., Resasco, J., Yu, Y., Asiri, A. M., & Yang, P. (2014) · Nature Communications · doi:10.1038/ncomms5948 · Cited by 1,374
Catalysis by Supported Single Metal Atoms
Liu, J. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b01534 · Cited by 1,331
New Approach to Fully Ordered fct-FePt Nanoparticles for Much Enhanced Electrocatalysis in Acid
Li, Q., Wu, L., Wu, G., Su, D., Lv, H., Zhang, S., Zhu, W., Casimir, A., Zhu, H., Mendoza-Garcia, A., et al. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b00320 · Cited by 460
Self-citationChan, C. W. A., Mahadi, A. H., Li, M. M.-J., Corbos, E. C., Tang, C., Jones, G., Kuo, W. C. H., Cookson, J., Brown, C. M., Bishop, P. T., et al. (2014) · Nature Communications · doi:10.1038/ncomms6787 · Cited by 279
Cited by
Facet engineering accelerates spillover hydrogenation on highly diluted metal nanocatalysts
Jiang, L., Liu, K., Hung, S.-F., Zhou, L., Qin, R., Zhang, Q., Liu, P., Gu, L., Chen, H. M., Fu, G., et al. (2020) · Nature Nanotechnology · doi:10.1038/s41565-020-0746-x · Cited by 380
Self-citationSarma, B. B., Maurer, F., Doronkin, D. E., & Grunwaldt, J.-D. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00495 · Cited by 291
Interstitial Hydrogen Atom Modulation to Boost Hydrogen Evolution in Pd-Based Alloy Nanoparticles
Fan, J., Cui, X., Yu, S., Gu, L., Zhang, Q., Meng, F., Peng, Z., Ma, L., Ma, J.-Y., Qi, K., et al. (2019) · ACS Nano · doi:10.1021/acsnano.9b05615 · Cited by 102
Self-citationZhang, R., Liu, Z., Zheng, S., Wang, L., Zhang, L., & Qiao, Z. (2023) · Advanced Materials · doi:10.1002/adma.202209635 · Cited by 98
Metadata
- Authors
- Feng, Q., Zhao, S., Wang, Y., Dong, J., Chen, W., He, D., Wang, D., Yang, J., Zhu, Y., Zhu, H., Gu, L., Li, Z., Liu, Y., Yu, R., Li, J., & Li, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-05-22
- Volume
- 139
- Issue
- 21
- Pages
- 7294-7301
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2613910893
- Cited by
- 480
- References
- 6
- FWCI
- 18.13
- Type
- journal article
- Language
- en
- Open access
- closed
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- Feng, Q., Zhao, S., Wang, Y., Dong, J., Chen, W., He, D., Wang, D., Yang, J., Zhu, Y., Zhu, H., Gu, L., Li, Z., Liu, Y., Yu, R., Li, J., & Li, Y. (2017). Isolated Single-Atom Pd Sites in Intermetallic Nanostructures: High Catalytic Selectivity for Semihydrogenation of Alkynes. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b01471
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