The DOI matches its Crossref record; 72 of the 72 references it cites were found in a registry or an index.
Multivariate Metal–Organic Frameworks as Multifunctional Heterogeneous Asymmetric Catalysts for Sequential Reactions
Abstract
The search for versatile heterogeneous catalysts with multiple active sites for broad asymmetric transformations has long been of great interest, but it remains a formidable synthetic challenge. Here we demonstrate that multivariate metal-organic frameworks (MTV-MOFs) can be used as an excellent platform to engineer heterogeneous catalysts featuring multiple and cooperative active sites. An isostructural series of 2-fold interpenetrated MTV-MOFs that contain up to three different chiral metallosalen catalysts was constructed and used as efficient and recyclable heterogeneous catalysts for a variety of asymmetric sequential alkene epoxidation/epoxide ring-opening reactions. Interpenetration of the frameworks brings metallosalen units adjacent to each other, allowing cooperative activation, which results in improved efficiency and enantioselectivity over the sum of the individual parts. The fact that manipulation of molecular catalysts in MTV-MOFs can control the activities and selectivities would facilitate the design of novel multifunctional materials for enantioselective processes.
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Cites
The Chemistry and Applications of Metal-Organic Frameworks
Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013) · Science · doi:10.1126/science.1230444 · Cited by 16,945
Single-crystal structure validation with the program PLATON
Spek, A. L. (2003) · Journal of Applied Crystallography · doi:10.1107/s0021889802022112 · Cited by 14,084
Metal–Organic Framework Materials as Chemical Sensors
Kreno, L. E., Leong, K., Farha, O. K., Allendorf, M., Van Duyne, R. P., & Hupp, J. T. (2012) · Chemical Reviews · doi:10.1021/cr200324t · Cited by 7,136
Carbon Dioxide Capture in Metal–Organic Frameworks
Sumida, K., Rogow, D. L., Mason, J. A., McDonald, T. M., Bloch, E. D., Herm, Z. R., Bae, T.-H., & Long, J. R. (2012) · Chemical Reviews · doi:10.1021/cr2003272 · Cited by 6,408
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Luminescent Functional Metal–Organic Frameworks
Cui, Y., Yue, Y., Qian, G., & Chen, B. (2012) · Chemical Reviews · doi:10.1021/cr200101d · Cited by 5,697
Self-citationLuminescent metal–organic frameworks for chemical sensing and explosive detection
Hu, Z., Deibert, B. J., & Li, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00010b · Cited by 4,169
Hydrogen Storage in Metal–Organic Frameworks
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Cited by
Metal–organic framework-derived porous materials for catalysis
Chen, Y.-Z., Zhang, R., Jiao, L., & Jiang, H.-L. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2018.02.008 · Cited by 1,015
Chiral Metal–Organic Frameworks
Gong, W., Chen, Z., Dong, J., Liu, Y., & Cui, Y. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00740 · Cited by 579
Self-citationDong, J., Han, X., Liu, Y., Li, H., & Cui, Y. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202004796 · Cited by 561
Self-citationChiral covalent organic frameworks: design, synthesis and property
Han, X., Yuan, C., Hou, B., Liu, L., Li, H., Liu, Y., & Cui, Y. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00009d · Cited by 478
Self-citationPore Chemistry of Metal–Organic Frameworks
Ji, Z., Wang, H., Canossa, S., Wuttke, S., & Yaghi, O. M. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202000238 · Cited by 459
Metadata
- Authors
- Xia, Q., Li, Z., Tan, C., Liu, Y., Gong, W., & Cui, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-06-06
- Volume
- 139
- Issue
- 24
- Pages
- 8259-8266
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2619930446
- Cited by
- 265
- References
- 72
- FWCI
- 12.68
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xia, Q., Li, Z., Tan, C., Liu, Y., Gong, W., & Cui, Y. (2017). Multivariate Metal–Organic Frameworks as Multifunctional Heterogeneous Asymmetric Catalysts for Sequential Reactions. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b03113
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