The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
3D Porphyrin-Based Covalent Organic Frameworks
Abstract
The design and synthesis of three-dimensional covalent organic frameworks (3D COFs) bearing photoelectric units have been considered as a big challenge. Herein, for the first time, we reported the targeted synthesis of two 3D porphyrin-based COFs (3D-Por-COF and 3D-CuPor-COF), starting from tetrahedral (3D- T d ) and square (2D- C 4 ) building blocks connected through [4 + 4] imine condensation reactions. On the basis of structural characterizations, 3D-Por-COF and 3D-CuPor-COF are microporous materials with high surface areas, and are proposed to adopt a 2-fold interpenetrated pts topology with Pmc 2 1 space group. Interestingly, both 3D COFs are photosensitive and can be used as heterogeneous catalyst for generating singlet oxygen under photoirradiation. However, 3D-Por-COF shows enhanced photocatalytic activity compared with 3D-CuPor-COF, indicating the properties of 3D porphyrin-based COFs can be tuned by metalation of porphyrin rings. The results reported here will greatly inspire us to design and synthesize 3D COFs bearing other metalloporphyrins for interesting applications (e.g., catalysis) in the future.
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Cites
Porphyrins as excellent dyes for dye-sensitized solar cells: recent developments and insights
Higashino, T., & Imahori, H. (2015) · Dalton Transactions · doi:10.1039/c4dt02756f · Cited by 582
Cited by
Covalent Organic Framework Photocatalysts: Structures and Applications
Wang, H., Wang, H., Wang, Z., Tang, L., Zeng, G., Xu, P., Chen, M., Xiong, T., Zhou, C., Li, X., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00278j · Cited by 1,301
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Dong, J., Han, X., Liu, Y., Li, H., & Cui, Y. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202004796 · Cited by 561
Beuerle, F., & Gole, B. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201710190 · Cited by 528
Metadata
- Authors
- Lin, G., Ding, H., Chen, R., Peng, Z., Wang, B., & Wang, C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-06-15
- Volume
- 139
- Issue
- 25
- Pages
- 8705-8709
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2622519202
- Cited by
- 517
- References
- 1
- FWCI
- 19.20
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lin, G., Ding, H., Chen, R., Peng, Z., Wang, B., & Wang, C. (2017). 3D Porphyrin-Based Covalent Organic Frameworks. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b04141
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