The DOI matches its Crossref record; 13 of the 13 references it cites were found in a registry or an index.
Highly Active, Nonprecious Electrocatalyst Comprising Borophene Subunits for the Hydrogen Evolution Reaction
Abstract
Developing nonprecious hydrogen evolution electrocatalysts that can work well at large current densities (e.g., at 1000 mA/cm 2: a value that is relevant for practical, large-scale applications) is of great importance for realizing a viable water-splitting technology. Herein we present a combined theoretical and experimental study that leads to the identification of α-phase molybdenum diboride (α-MoB 2 ) comprising borophene subunits as a noble metal-free, superefficient electrocatalyst for the hydrogen evolution reaction (HER). Our theoretical finding indicates, unlike the surfaces of Pt- and MoS 2 -based catalysts, those of α-MoB 2 can maintain high catalytic activity for HER even at very high hydrogen coverage and attain a high density of efficient catalytic active sites. Experiments confirm α-MoB 2 can deliver large current densities in the order of 1000 mA/cm 2, and also has excellent catalytic stability during HER. The theoretical and experimental results show α-MoB 2 ’s catalytic activity, especially at large current densities, is due to its high conductivity, large density of efficient catalytic active sites and good mass transport property.
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Citations
Cites
Biomimetic Hydrogen Evolution: MoS 2 Nanoparticles as Catalyst for Hydrogen Evolution
Hinnemann, B., Moses, P. G., Bonde, J., Jørgensen, K. P., Nielsen, J. H., Horch, S., Chorkendorff, I., & Nørskov, J. K. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0504690 · Cited by 4,065
Enhanced Hydrogen Evolution Catalysis from Chemically Exfoliated Metallic MoS 2 Nanosheets
Lukowski, M. A., Daniel, A. S., Meng, F., Forticaux, A., Li, L., & Jin, S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja404523s · Cited by 3,341
Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds
Cook, T. R., Dogutan, D. K., Reece, S. Y., Surendranath, Y., Teets, T. S., & Nocera, D. G. (2010) · Chemical Reviews · doi:10.1021/cr100246c · Cited by 3,064
Li, H., Tsai, C., Koh, A. L., Cai, L., Contryman, A. W., Fragapane, A. H., Zhao, J., Han, H. S., Manoharan, H. C., Abild-Pedersen, F., et al. (2016) · Nature Materials · doi:10.1038/nmat4465 · Cited by 2,529
Self-citationNanostructured hydrotreating catalysts for electrochemical hydrogen evolution
Morales-Guio, C. G., Stern, L.-A., & Hu, X. (2014) · Chemical Society Reviews · doi:10.1039/c3cs60468c · Cited by 2,437
New insights into the electrochemical hydrogen oxidation and evolution reaction mechanism
Durst, J., Siebel, A., Simon, C., Hasché, F., Herranz, J., & Gasteiger, H. A. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee00440j · Cited by 1,666
Molybdenum Boride and Carbide Catalyze Hydrogen Evolution in both Acidic and Basic Solutions
Vrubel, H., & Hu, X. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201207111 · Cited by 1,302
Skúlason, E., Tripkovic, V., Björketun, M. E., Gudmundsdóttir, S., Karlberg, G., Rossmeisl, J., Bligaard, T., Jónsson, H., & Nørskov, J. K. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp1048887 · Cited by 1,271
Lu, Z., Zhu, W., Yu, X., Zhang, H., Li, Y., Sun, X., Wang, X., Wang, H., Wang, J., Luo, J., et al. (2014) · Advanced Materials · doi:10.1002/adma.201304759 · Cited by 1,025
Cao, B., Veith, G. M., Neuefeind, J. C., Adzic, R. R., & Khalifah, P. G. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4081056 · Cited by 998
Planar hexagonal B36 as a potential basis for extended single-atom layer boron sheets
Piazza, Z. A., Hu, H.-S., Li, W.-L., Zhao, Y.-F., Li, J., & Wang, L.-S. (2014) · Nature Communications · doi:10.1038/ncomms4113 · Cited by 864
Zhu, L., Lin, H., Li, Y., Liao, F., Lifshitz, Y., Sheng, M., Lee, S.-T., & Shao, M. (2016) · Nature Communications · doi:10.1038/ncomms12272 · Cited by 351
Controlled Exfoliation of MoS2 Crystals into Trilayer Nanosheets
Fan, X., Xu, P., Li, Y. C., Zhou, D., Sun, Y., Nguyen, M. A. T., Terrones, M., & Mallouk, T. E. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b01502 · Cited by 248
Cited by
Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting
Quan, L., Jiang, H., Mei, G., Sun, Y., & You, B. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00332 · Cited by 874
Recent Advances in Design of Electrocatalysts for High‐Current‐Density Water Splitting
Luo, Y., Zhang, Z., Chhowalla, M., & Liu, B. (2022) · Advanced Materials · doi:10.1002/adma.202108133 · Cited by 854
Luo, Y., Tang, L., Khan, U., Yu, Q., Cheng, H.-M., Zou, X., & Liu, B. (2019) · Nature Communications · doi:10.1038/s41467-018-07792-9 · Cited by 713
Self-citationYu, X., Yu, Z.-Y., Zhang, X.-L., Zheng, Y.-R., Duan, Y., Gao, Q., Wu, R., Sun, B., Gao, M.-R., Wang, G., et al. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b02527 · Cited by 568
Fu, H. Q., Zhou, M., Liu, P. F., Liu, P., Yin, H., Sun, K. Z., Yang, H. G., Al-Mamun, M., Hu, P., Wang, H.-F., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c01094 · Cited by 508
Metadata
- Authors
- Chen, Y., Yu, G., Chen, W., Liu, Y., Li, G.-D., Zhu, P., Tao, Q., Li, Q., Liu, J., Shen, X., Li, H., Huang, X., Wang, D., Asefa, T., & Zou, X.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-07-13
- Volume
- 139
- Issue
- 36
- Pages
- 12370-12373
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2727161249
- Cited by
- 445
- References
- 13
- FWCI
- 12.67
- Type
- journal article
- Language
- en
- Open access
- closed
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