The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Identifying the Structural Basis for the Increased Stability of the Solid Electrolyte Interphase Formed on Silicon with the Additive Fluoroethylene Carbonate
Open accessAbstract
To elucidate the role of fluoroethylene carbonate (FEC) as an additive in the standard carbonate-based electrolyte for Li-ion batteries, the solid electrolyte interphase (SEI) formed during electrochemical cycling on silicon anodes was analyzed with a combination of solution and solid-state NMR techniques, including dynamic nuclear polarization. To facilitate characterization via 1D and 2D NMR, we synthesized 13 C-enriched FEC, ultimately allowing a detailed structural assignment of the organic SEI. We find that the soluble poly(ethylene oxide)-like linear oligomeric electrolyte breakdown products that are observed after cycling in the standard ethylene carbonate-based electrolyte are suppressed in the presence of 10 vol% FEC additive. FEC is first defluorinated to form soluble vinylene carbonate and vinoxyl species, which react to form both soluble and insoluble branched ethylene-oxide-based polymers. No evidence for branched polymers is observed in the absence of FEC.
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Cites
Electrolytes and Interphases in Li-Ion Batteries and Beyond
Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
Michan, A. L., Parimalam, B. S., Leskes, M., Kerber, R. N., Yoon, T., Grey, C. P., & Lucht, B. L. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b02282 · Cited by 541
Self-citationChalasani, D., Li, J., Jackson, N. M., Payne, M., & Lucht, B. L. (2012) · Journal of Power Sources · doi:10.1016/j.jpowsour.2012.02.004 · Cited by 53
Cited by
Review on modeling of the anode solid electrolyte interphase (SEI) for lithium-ion batteries
Wang, A., Kadam, S., Li, H., Shi, S., & Qi, Y. (2018) · npj Computational Materials · doi:10.1038/s41524-018-0064-0 · Cited by 1,639
Designing polymers for advanced battery chemistries
Lopez, J., Mackanic, D. G., Cui, Y., & Bao, Z. (2019) · Nature Reviews Materials · doi:10.1038/s41578-019-0103-6 · Cited by 894
Hou, T., Yang, G., Rajput, N. N., Self, J., Park, S.-W., Nanda, J., & Persson, K. A. (2019) · Nano Energy · doi:10.1016/j.nanoen.2019.103881 · Cited by 470
Electrolyte Oxidation Pathways in Lithium-Ion Batteries
Rinkel, B. L. D., Hall, D. S., Temprano, I., & Grey, C. P. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c06363 · Cited by 455
Self-citationFluorine and Lithium: Ideal Partners for High‐Performance Rechargeable Battery Electrolytes
von Aspern, N., Röschenthaler, G. ‐., Winter, M., & Cekic‐Laskovic, I. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201901381 · Cited by 429
Metadata
- Authors
- Jin, Y., Kneusels, N.-J. H., Magusin, P. C. M. M., Kim, G., Castillo-Martínez, E., Marbella, L. E., Kerber, R. N., Howe, D. J., Paul, S., Liu, T., & Grey, C. P.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-10-13
- Volume
- 139
- Issue
- 42
- Pages
- 14992-15004
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2757623388
- Cited by
- 291
- References
- 3
- FWCI
- 8.17
- Type
- journal article
- Language
- en
- Open access
- green
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- Jin, Y., Kneusels, N.-J. H., Magusin, P. C. M. M., Kim, G., Castillo-Martínez, E., Marbella, L. E., Kerber, R. N., Howe, D. J., Paul, S., Liu, T., & Grey, C. P. (2017). Identifying the Structural Basis for the Increased Stability of the Solid Electrolyte Interphase Formed on Silicon with the Additive Fluoroethylene Carbonate. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b06834
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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