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Cited by 358

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Straightforward Loading of Imidazole Molecules into Metal–Organic Framework for High Proton Conduction

Ye, Yingxiang, Guo, Weigang, Wang, Lihua, Li, Ziyin, Song, Zhengju, Chen, Jun, Zhang, Zhangjing, Xiang, Shengchang, Chen, Banglin·2017·Journal of the American Chemical Society

Abstract

A one-step straightforward strategy has been developed to incorporate free imidazole molecules into a highly stable metal–organic framework ( NENU-3, ([Cu 12 (BTC) 8 (H 2 O) 12 ][HPW 12 O 40 ])·Guest). The resulting material Im@(NENU-3) exhibits a very high proton conductivity of 1.82 × 10 –2 S cm –1 at 90% RH and 70 °C, which is significantly higher than 3.16 × 10 –4 S cm –1 for Im-Cu@(NENU-3a) synthesized through a two-step approach with mainly terminal bound imidazole molecules inside pores. Single crystal structure reveals that imidazole molecules in Im-Cu@(NENU-3a) isolate lattice water molecules and then block proton transport pathway, whereas high concentration of free imidazole molecules within Im@(NENU-3) significantly facilitate successive proton-hopping pathways through formation of hydrogen bonded networks.

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Metadata

Authors
Ye, Y., Guo, W., Wang, L., Li, Z., Song, Z., Chen, J., Zhang, Z., Xiang, S., & Chen, B.
Venue
Journal of the American Chemical Society
Published
2017-10-31
Volume
139
Issue
44
Pages
15604-15607
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2765646140
Cited by
358
References
1
FWCI
16.33
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Straightforward Loading of Imidazole Molecules into Metal–Organic Framework for High Proton Conduction. https://app.cochat.ai/papers/10.1021/jacs.7b09163
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Ye, Y., Guo, W., Wang, L., Li, Z., Song, Z., Chen, J., Zhang, Z., Xiang, S., & Chen, B. (2017). Straightforward Loading of Imidazole Molecules into Metal–Organic Framework for High Proton Conduction. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b09163

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