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Straightforward Loading of Imidazole Molecules into Metal–Organic Framework for High Proton Conduction
Abstract
A one-step straightforward strategy has been developed to incorporate free imidazole molecules into a highly stable metal–organic framework ( NENU-3, ([Cu 12 (BTC) 8 (H 2 O) 12 ][HPW 12 O 40 ])·Guest). The resulting material Im@(NENU-3) exhibits a very high proton conductivity of 1.82 × 10 –2 S cm –1 at 90% RH and 70 °C, which is significantly higher than 3.16 × 10 –4 S cm –1 for Im-Cu@(NENU-3a) synthesized through a two-step approach with mainly terminal bound imidazole molecules inside pores. Single crystal structure reveals that imidazole molecules in Im-Cu@(NENU-3a) isolate lattice water molecules and then block proton transport pathway, whereas high concentration of free imidazole molecules within Im@(NENU-3) significantly facilitate successive proton-hopping pathways through formation of hydrogen bonded networks.
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Cites
Metal–organic frameworks as platforms for clean energy
Li, S.-L., & Xu, Q. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40507a · Cited by 970
Cited by
Proton Transport in Metal–Organic Frameworks
Lim, D.-W., & Kitagawa, H. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00842 · Cited by 689
Li, W.-H., Deng, W.-H., Wang, G.-E., & Xu, G. (2020) · EnergyChem · doi:10.1016/j.enchem.2020.100029 · Cited by 373
Polyoxometalate@Metal–Organic Framework Composites as Effective Photocatalysts
Liu, Y., Tang, C., Cheng, M., Chen, M., Chen, S., Lei, L., Chen, Y., Yi, H., Fu, Y., & Li, L. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c03866 · Cited by 253
Metadata
- Authors
- Ye, Y., Guo, W., Wang, L., Li, Z., Song, Z., Chen, J., Zhang, Z., Xiang, S., & Chen, B.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-10-31
- Volume
- 139
- Issue
- 44
- Pages
- 15604-15607
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2765646140
- Cited by
- 358
- References
- 1
- FWCI
- 16.33
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ye, Y., Guo, W., Wang, L., Li, Z., Song, Z., Chen, J., Zhang, Z., Xiang, S., & Chen, B. (2017). Straightforward Loading of Imidazole Molecules into Metal–Organic Framework for High Proton Conduction. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b09163
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