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Colloidal Synthesis of Double Perovskite Cs2AgInCl6 and Mn-Doped Cs2AgInCl6 Nanocrystals
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Abstract We show here the first colloidal synthesis of double perovskite Cs2AgInCl6 nanocrystals (NCs) with a control over their size distribution. In our approach, metal carboxylate precursors and ligands (oleylamine and oleic acid) are dissolved in diphenyl ether and reacted at 105 °C with benzoyl chloride. The resulting Cs2AgInCl6 NCs exhibit the expected double perovskite crystal structure, are stable under air, and show a broad spectrum white photoluminescence (PL) with quantum yield of ∼1.6 ± 1%. The optical properties of these NCs were improved by synthesizing Mn-doped Cs2AgInCl6 NCs through the simple addition of Mn-acetate to the reaction mixture. The NC products were characterized by the same double perovskite crystal structure, and Mn doping levels up to 1.5%, as confirmed by elemental analyses. The effective incorporation of Mn ions inside Cs2AgInCl6 NCs was also proved by means of electron spin resonance spectroscopy. A bright orange emission characterized our Mn-doped Cs2AgInCl6 NCs with a PL quantum yield as high as ∼16 ± 4%.
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Saliba, M., Matsui, T., Seo, J.-Y., Domanski, K., Correa-Baena, J.-P., Nazeeruddin, M. K., Zakeeruddin, S. M., Tress, W., Abate, A., Hagfeldt, A., et al. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03874j · Cited by 5,440
Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals
Akkerman, Q. A., Rainò, G., Kovalenko, M. V., & Manna, L. (2018) · Nature Materials · doi:10.1038/s41563-018-0018-4 · Cited by 2,287
Self-citationSlavney, A. H., Hu, T., Lindenberg, A. M., & Karunadasa, H. I. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b13294 · Cited by 2,204
Optical properties of manganese-doped nanocrystals of ZnS
Bhargava, R. N., Gallagher, D., Hong, X., & Nurmikko, A. (1994) · Physical Review Letters · doi:10.1103/physrevlett.72.416 · Cited by 1,994
Cs2AgBiX6 (X = Br, Cl): New Visible Light Absorbing, Lead-Free Halide Perovskite Semiconductors
McClure, E. T., Ball, M. R., Windl, W., & Woodward, P. M. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b04231 · Cited by 1,674
Bismuth Based Hybrid Perovskites A3Bi2I9 (A: Methylammonium or Cesium) for Solar Cell Application
Park, B., Philippe, B., Zhang, X., Rensmo, H., Boschloo, G., & Johansson, E. M. J. (2015) · Advanced Materials · doi:10.1002/adma.201501978 · Cited by 1,269
Cs2InAgCl6: A New Lead-Free Halide Double Perovskite with Direct Band Gap
Volonakis, G., Haghighirad, A. A., Milot, R. L., Sio, W. H., Filip, M. R., Wenger, B., Johnston, M. B., Herz, L. M., Snaith, H. J., & Giustino, F. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b02682 · Cited by 1,176
Lead-Free Halide Double Perovskites via Heterovalent Substitution of Noble Metals
Volonakis, G., Filip, M. R., Haghighirad, A. A., Sakai, N., Wenger, B., Snaith, H. J., & Giustino, F. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b00376 · Cited by 1,146
Toward Lead-Free Perovskite Solar Cells
Giustino, F., & Snaith, H. J. (2016) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00499 · Cited by 1,141
Design of Lead-Free Inorganic Halide Perovskites for Solar Cells via Cation-Transmutation
Zhao, X.-G., Yang, J.-H., Fu, Y., Yang, D., Xu, Q., Yu, L., Wei, S.-H., & Zhang, L. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b09645 · Cited by 1,003
Synthesis and Optical Properties of Lead-Free Cesium Tin Halide Perovskite Nanocrystals
Jellicoe, T. C., Richter, J. M., Glass, H. F. J., Tabachnyk, M., Brady, R., Dutton, S. E., Rao, A., Friend, R. H., Credgington, D., Greenham, N. C., et al. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b13470 · Cited by 998
(2020) · INDIGO (University of Illinois at Chicago) · doi:10.1021/jacs.5b13294.s002 · Cited by 892
Forging Colloidal Nanostructures via Cation Exchange Reactions
De Trizio, L., & Manna, L. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00739 · Cited by 761
Self-citationFilip, M. R., Hillman, S., Haghighirad, A. A., Snaith, H. J., & Giustino, F. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b01041 · Cited by 750
Strongly emissive perovskite nanocrystal inks for high-voltage solar cells
Akkerman, Q. A., Gandini, M., Di Stasio, F., Rastogi, P., Palazon, F., Bertoni, G., Ball, J. M., Prato, M., Petrozza, A., & Manna, L. (2016) · Nature Energy · doi:10.1038/nenergy.2016.194 · Cited by 721
Self-citationMeng, W., Wang, X., Xiao, Z., Wang, J., Mitzi, D. B., & Yan, Y. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b01042 · Cited by 672
Imran, M., Caligiuri, V., Wang, M., Goldoni, L., Prato, M., Krahne, R., De Trizio, L., & Manna, L. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b13477 · Cited by 645
Self-citationPradhan, N. C., & Peng, X. (2007) · Journal of the American Chemical Society · doi:10.1021/ja068360v · Cited by 600
Progress on Perovskite Materials and Solar Cells with Mixed Cations and Halide Anions
Ono, L. K., Juarez-Perez, E. J., & Qi, Y. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b06001 · Cited by 593
Zhang, J., Yang, Y., Deng, H., Farooq, U., Yang, X., Khan, J., Tang, J., & Song, H. (2017) · ACS Nano · doi:10.1021/acsnano.7b04683 · Cited by 581
The Dawn of Lead‐Free Perovskite Solar Cell: Highly Stable Double Perovskite Cs2AgBiBr6 Film
Wu, C., Zhang, Q., Liu, Y., Luo, W., Guo, X., Huang, Z., Ting, H., Sun, W., Zhong, X., Wei, S., et al. (2018) · Advanced Science · doi:10.1002/advs.201700759 · Cited by 571
Bandgap Engineering of Lead‐Free Double Perovskite Cs2AgBiBr6 through Trivalent Metal Alloying
Du, K., Meng, W., Wang, X., Yan, Y., & Mitzi, D. B. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201703970 · Cited by 563
Can Pb-Free Halide Double Perovskites Support High-Efficiency Solar Cells?
Savory, C. N., Walsh, A., & Scanlon, D. O. (2016) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00471 · Cited by 554
Creutz, S. E., Crites, E. N., De Siena, M. C., & Gamelin, D. R. (2018) · Nano Letters · doi:10.1021/acs.nanolett.7b04659 · Cited by 521
Zhou, J., Xia, Z., Molokeev, M. S., Zhang, X., Peng, D., & Liu, Q. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta04690a · Cited by 464
Doping Mn2+ in Lead Halide Perovskite Nanocrystals: Successes and Challenges
Guria, A. K., Dutta, S. K., Adhikari, S. D., & Pradhan, N. (2017) · ACS Energy Letters · doi:10.1021/acsenergylett.7b00177 · Cited by 452
Luo, J., Li, S., Wu, H., Zhou, Y., Li, Y., Liu, J., Li, J., Li, K., Yi, F., Niu, G., et al. (2018) · ACS Photonics · doi:10.1021/acsphotonics.7b00837 · Cited by 442
Gao, W., Ran, C., Xi, J., Jiao, B., Zhang, W., Wu, M., Hou, X., & Wu, Z. (2018) · ChemPhysChem · doi:10.1002/cphc.201800346 · Cited by 436
Cu–In Halide Perovskite Solar Absorbers
Zhao, X.-G., Yang, D., Sun, Y., Li, T., Zhang, L., Yu, L., & Zunger, A. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b02120 · Cited by 428
Designing indirect–direct bandgap transitions in double perovskites
Tran, T. T., Panella, J. R., Chamorro, J. R., Morey, J. R., & McQueen, T. M. (2017) · Materials Horizons · doi:10.1039/c7mh00239d · Cited by 388
Wang, A., Yan, X., Zhang, M., Sun, S., Yang, M., Shen, W., Pan, X., Wang, P., & Deng, Z. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b01329 · Cited by 383
Preparation of cubic chloro complex compounds of trivalent metals: Cs2NaMCl6
Morss, L. R., Siegal, M. P., Stenger, L., & Edelstein, N. M. (1970) · Inorganic Chemistry · doi:10.1021/ic50089a034 · Cited by 370
Bekenstein, Y., Dahl, J. C., Huang, J., Osowiecki, W. T., Swabeck, J. K., Chan, E. M., Yang, P., & Alivisatos, A. P. (2018) · Nano Letters · doi:10.1021/acs.nanolett.8b00560 · Cited by 354
Wei, F., Deng, Z., Sun, S., Xie, F., Kieslich, G., Evans, D. M., Carpenter, M. A., Bristowe, P. D., & Cheetham, A. K. (2016) · Materials Horizons · doi:10.1039/c6mh00053c · Cited by 342
Beyond Colloidal Cesium Lead Halide Perovskite Nanocrystals: Analogous Metal Halides and Doping
Swarnkar, A., Ravi, V. K., & Nag, A. (2017) · ACS Energy Letters · doi:10.1021/acsenergylett.7b00191 · Cited by 330
Deng, Z., Wei, F., Sun, S., Kieslich, G., Cheetham, A. K., & Bristowe, P. D. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta05817e · Cited by 311
Doped Halide Perovskite Nanocrystals for Reabsorption-Free Luminescent Solar Concentrators
Meinardi, F., Akkerman, Q. A., Bruni, F., Park, S., Mauri, M., Dang, Z., Manna, L., & Brovelli, S. (2017) · ACS Energy Letters · doi:10.1021/acsenergylett.7b00701 · Cited by 284
Self-citationDesigned Assembly and Integration of Colloidal Nanocrystals for Device Applications
Yang, J., Choi, M. K., Kim, D., & Hyeon, T. (2016) · Advanced Materials · doi:10.1002/adma.201502851 · Cited by 256
Hysteresis-Free Lead-Free Double-Perovskite Solar Cells by Interface Engineering
Pantaler, M., Cho, K. T., Queloz, V. I. E., García‐Benito, I., Fettkenhauer, C., Anusca, I., Nazeeruddin, M. K., Lupascu, D. C., & Grancini, G. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b00871 · Cited by 239
Synthesis and luminescence of Mn-doped Cs2AgInCl6 double perovskites
K., N. N., & Nag, A. (2018) · Chemical Communications · doi:10.1039/c8cc01982g · Cited by 227
Lei, L.-Z., Shi, Z.-F., Li, Y., Ma, Z.-Z., Zhang, F., Xu, T.-T., Tian, Y.-T., Wu, D., Li, X.-J., & Du, G.-T. (2018) · Journal of Materials Chemistry C · doi:10.1039/c8tc02305k · Cited by 202
High-Throughput Screening of Lead-Free Perovskite-like Materials for Optoelectronic Applications
Jain, A., Voznyy, O., & Sargent, E. H. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b02221 · Cited by 180
Tuning Exciton–Mn2+ Energy Transfer in Mixed Halide Perovskite Nanocrystals
Xu, K., & Meijerink, A. (2018) · Chemistry of Materials · doi:10.1021/acs.chemmater.8b02157 · Cited by 147
Syntheses and Applications of Mn-Doped II-VI Semiconductor Nanocrystals
Yang, H., Santra, S., & Holloway, P. H. (2005) · Journal of Nanoscience and Nanotechnology · doi:10.1166/jnn.2005.308 · Cited by 137
Alternative Perovskites for Photovoltaics
Jodlowski, A. D., Rodríguez‐Padrón, D., Luque, R., & de Miguel, G. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201703120 · Cited by 137
Palazón, F., Doğan, S., Marras, S., Locardi, F., Nelli, I., Rastogi, P., Ferretti, M., Prato, M., Krahne, R., & Manna, L. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b03389 · Cited by 120
Self-citationFeng, H., Deng, W., Yang, K., Huang, J., & Zeng, X. C. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b00138 · Cited by 115
Ligand-Free, Quantum-Confined Cs2SnI6 Perovskite Nanocrystals
Dolzhnikov, D. S., Wang, C., Xu, Y., Kanatzidis, M. G., & Weiss, E. A. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b02803 · Cited by 112
Deng, Z., Wei, F., Brivio, F., Wu, Y., Sun, S., Bristowe, P. D., & Cheetham, A. K. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b02322 · Cited by 91
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Goh, M., 공광훈, & 강창희 (2013) · Cited by 19
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Bi3+‐Er3+ and Bi3+‐Yb3+ Codoped Cs2AgInCl6 Double Perovskite Near‐Infrared Emitters
Arfin, H., Kaur, J., Sheikh, T., Chakraborty, S., & Nag, A. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202002721 · Cited by 359
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Locardi, F., Sartori, E., Buha, J., Zito, J., Prato, M., Pinchetti, V., Zaffalon, M. L., Ferretti, M., Brovelli, S., Infante, I., et al. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.9b01274 · Cited by 268
Self-citation
Metadata
- Authors
- Locardi, F., Cirignano, M., Baranov, D., Dang, Z., Prato, M., Drago, F., Ferretti, M., Pinchetti, V., Fanciulli, M., Brovelli, S., De Trizio, L., & Manna, L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-09-10
- Volume
- 140
- Issue
- 40
- Pages
- 12989-12995
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2891026324
- Cited by
- 578
- References
- 50
- FWCI
- 20.32
- Type
- journal article
- Language
- en
- Open access
- hybrid
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