The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Fast Ion Transport Pathway Provided by Polyethylene Glycol Confined in Covalent Organic Frameworks
Abstract
Covalent organic frameworks (COFs) with well-tailored channels are able to accommodate ions and offer their conduction pathway. However, due to strong Coulombic interaction and the lack of transport medium, directly including lithium salts into the channels of COFs results in limited ion transport capability. Herein, we propose a strategy of incorporating low-molecular-weight polyethylene glycol (PEG) into COFs with anionic, neutral, or cationic skeletons to accelerate Li + conduction. The PEG confined in the well-aligned channels retains high flexibility and Li + solvating ability. The ion conductivity of PEG included in a cationic COF can reach 1.78 × 10 –3 S cm –1 at 120 °C. The simplicity of this strategy as well as the diversity of crystalline porous materials holds great promise to design high-performance all-solid-state ion conductors.
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Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Cited by
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Metadata
- Authors
- Guo, Z., Zhang, Y., Dong, Y., Li, J., Li, S., Shao, P., Feng, X., & Wang, B.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-01-18
- Volume
- 141
- Issue
- 5
- Pages
- 1923-1927
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2911181015
- Cited by
- 331
- References
- 1
- FWCI
- 14.36
- Type
- journal article
- Language
- en
- Open access
- closed
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- Guo, Z., Zhang, Y., Dong, Y., Li, J., Li, S., Shao, P., Feng, X., & Wang, B. (2019). Fast Ion Transport Pathway Provided by Polyethylene Glycol Confined in Covalent Organic Frameworks. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.8b13551
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