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Three-dimensional Salphen-based Covalent–Organic Frameworks as Catalytic Antioxidants

Yan, Shichen, Guan, Xinyu, Li, Hui, Li, Daohao, Xue, Ming, Yan, Yushan, Valtchev, Valentin, Qiu, Shilun, Fang, Qianrong·2019·Journal of the American Chemical Society

Abstract

The development of three-dimensional (3D) functionalized covalent-organic frameworks (COFs) is of critical importance for expanding their potential applications. However, the introduction of functional groups in 3D COFs remains largely unexplored. Herein, we report the first example of 3D Salphen-based COFs (3D-Salphen-COFs) and their metal-containing counterparts (3D-M-Salphen-COFs). These Salphen-based COFs exhibit high crystallinity and specific surface area in addition to excellent chemical stability. Furthermore, the Cu(II)-Salphen COF displays high activity in the removal of superoxide radicals. This study not only presents a new pathway to construct 3D functionalized COFs but also promotes their applications in biology and medicine.

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Metadata

Authors
Yan, S., Guan, X., Li, H., Li, D., Xue, M., Yan, Y., Valtchev, V., Qiu, S., & Fang, Q.
Venue
Journal of the American Chemical Society
Published
2019-02-04
Volume
141
Issue
7
Pages
2920-2924
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2912550750
Cited by
252
References
0
FWCI
12.68
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Three-dimensional Salphen-based Covalent–Organic Frameworks as Catalytic Antioxidants. https://app.cochat.ai/papers/10.1021/jacs.9b00485
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Yan, S., Guan, X., Li, H., Li, D., Xue, M., Yan, Y., Valtchev, V., Qiu, S., & Fang, Q. (2019). Three-dimensional Salphen-based Covalent–Organic Frameworks as Catalytic Antioxidants. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.9b00485

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