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Triazine Functionalized Porous Covalent Organic Framework for Photo-organocatalytic E–Z Isomerization of Olefins
Abstract
Visible light-mediated photocatalytic organic transformation has drawn significant attention as an alternative process for replacing thermal reactions. Although precious metal/organic dyes based homogeneous photocatalysts have been developed, their toxic and nonreusable nature makes them inappropriate for large-scale production. Therefore, we have synthesized a triazine and a keto functionalized nonmetal based covalent organic framework (TpTt) for heterogeneous photocatalysis. As the catalyst shows significant absorption of visible light, it has been applied for the photocatalytic uphill conversion of trans-stilbene to cis-stilbene in the presence of blue light-emitting diodes with broad substrate scope via an energy transfer process.
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Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Cited by
Covalent Organic Framework Photocatalysts: Structures and Applications
Wang, H., Wang, H., Wang, Z., Tang, L., Zeng, G., Xu, P., Chen, M., Xiong, T., Zhou, C., Li, X., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00278j · Cited by 1,301
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Metadata
- Authors
- Bhadra, M., Kandambeth, S., Sahoo, M. K., Addicoat, M., Balaraman, E., & Banerjee, R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-04-04
- Volume
- 141
- Issue
- 15
- Pages
- 6152-6156
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2935182178
- Cited by
- 403
- References
- 1
- FWCI
- 17.63
- Type
- journal article
- Language
- en
- Open access
- closed
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- Bhadra, M., Kandambeth, S., Sahoo, M. K., Addicoat, M., Balaraman, E., & Banerjee, R. (2019). Triazine Functionalized Porous Covalent Organic Framework for Photo-organocatalytic E–Z Isomerization of Olefins. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.9b01891
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