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Adsorption Equilibrium of Methane, Carbon Dioxide, and Nitrogen on Zeolite 13X at High Pressures
Abstract
High-pressure adsorption of methane, carbon dioxide, and nitrogen on zeolite 13X was measured in the pressure range (0 to 5) MPa at (298, 308, and 323) K and fitted with the Toth and multisite Langmuir models. Isosteric heats of adsorption were (12.8, 15.3, and 37.2) kJ/mol for nitrogen, methane, and carbon dioxide respectively, which indicate a very strong adsorption of carbon dioxide. The preferential adsorption capacity of CO 2 on zeolite 13X was much higher than for the other gases, indicating that zeolite 13X can be used for methane purification from natural gas or for carbon dioxide sequestration from flue gas.
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Citations
Cited by
Millward, A. R., & Yaghi, O. M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0570032 · Cited by 2,876
Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
Nugent, P., Belmabkhout, Y., Burd, S. D., Cairns, A. J., Luebke, R., Forrest, K., Pham, T., Ma, S., Space, B., Wojtas, L., et al. (2013) · Nature · doi:10.1038/nature11893 · Cited by 2,387
Carbon capture and storage update
Boot-Handford, M. E., Abanades, J. C., Anthony, E. J., Blunt, M. J., Brandani, S., Mac Dowell, N., Fernández, J. R., Ferrari, M.-C., Gross, R., Hallett, J. P., et al. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee42350f · Cited by 2,386
Post-Combustion CO 2 Capture Using Solid Sorbents: A Review
Samanta, A., Zhao, A., Shimizu, G. K. H., Sarkar, P., & Gupta, R. (2012) · Industrial & Engineering Chemistry Research · doi:10.1021/ie200686q · Cited by 1,889
A Review of CO2 Capture by Absorption and Adsorption
Yu, C.-H., Huang, C.-H., & Tan, C.-S. (2012) · Aerosol and Air Quality Research · doi:10.4209/aaqr.2012.05.0132 · Cited by 1,730
Metadata
- Authors
- Cavenati, S., Grande, C. A., & Rodrigues, A. E.
- Venue
- Journal of Chemical & Engineering Data
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-06-05
- Volume
- 49
- Issue
- 4
- Pages
- 1095-1101
- ISSN
- 0021-9568 (ISSN-L)
- 1520-5134
- OpenAlex
- W2005005410
- Cited by
- 1,147
- References
- 0
- FWCI
- 23.17
- Type
- journal article
- Language
- en
- Open access
- closed
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- Cavenati, S., Grande, C. A., & Rodrigues, A. E. (2004). Adsorption Equilibrium of Methane, Carbon Dioxide, and Nitrogen on Zeolite 13X at High Pressures. Journal of Chemical & Engineering Data. https://doi.org/10.1021/je0498917
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