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Solubility of CO2 in the Ionic Liquids [bmim][CH3SO4] and [bmim][PF6]

Kumełan, Jacek, Pérez-Salado Kamps, Álvaro, Tuma, Dirk, Maurer, Gerd·2006·Journal of Chemical & Engineering Data

Abstract

A high-pressure view-cell technique based on the synthetic method was used to determine the solubility of carbon dioxide in the ionic liquid 1- n -butyl-3-methylimidazolium methyl sulfate ([bmim][CH 3 SO 4 ]). The temperature ranged from 293.2 K to 413.1 K, the pressure and the carbon dioxide molality reached up to ∼10 MPa and ∼3.3 mol of CO 2 ·(kg of [bmim][CH 3 SO 4 ]) -1, respectively. The (extended) Henry's law was successfully applied to correlate the solubility pressures. The final results for the Henry's constant (at zero pressure) of carbon dioxide in [bmim][CH 3 SO 4 ] (on the molality scale) are correlated within the estimated uncertainty (± 1.3 %) by ln( /MPa) = 7.2738 − 1775/( T /K) − 0.002033( T /K). Furthermore, some small corrections were applied to the experimental results for the solubility of carbon dioxide in the ionic liquid 1- n -butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF 6 ]) reported in previous work. The corrected values for the Henry's constant of carbon dioxide in [bmim][PF 6 ] only slightly and systematically deviate (by about −2 % at given temperature) from the values reported previously.

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Metadata

Authors
Kumełan, J., Pérez-Salado Kamps, Á., Tuma, D., & Maurer, G.
Venue
Journal of Chemical & Engineering Data
Published
2006-07-13
Volume
51
Issue
5
Pages
1802-1807
ISSN
  • 0021-9568 (ISSN-L)
  • 1520-5134
OpenAlex
W2057628303
Cited by
171
References
1
FWCI
4.84
Type
journal article
Language
en
Open access
closed

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Kumełan, J., Pérez-Salado Kamps, Á., Tuma, D., & Maurer, G. (2006). Solubility of CO2 in the Ionic Liquids [bmim][CH3SO4] and [bmim][PF6]. Journal of Chemical & Engineering Data. https://doi.org/10.1021/je060190e

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