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Physical Properties of Pure 1-Ethyl-3-methylimidazolium Ethylsulfate and Its Binary Mixtures with Ethanol and Water at Several Temperatures
Abstract
This paper reports on the synthesis and the physical properties of the ionic liquid 1-ethyl-3-methylimidazolium ethylsulfate (EMISE). Experimental densities, speeds of sound and refractive indices were determined from (288.15 to 343.15) K. Dynamic viscosities were measured from (298.15 to 343.15) K and surface tension were measured from (288.15 to 313.15) K for pure ionic liquid. Densities, dynamic viscosities, speeds of sound, and isentropic compressibilities have been determined over the whole composition range for ethanol (1) + EMISE (2) and water (1) + EMISE (2) binary systems at T = (298.15, 313.15, and 328.15) K and atmospheric pressure. Excess molar volumes, viscosity deviations, and deviations in isentropic compressibility for the binary systems were fitted to a Redlich−Kister equation to determine the fitting parameters and the root mean square deviations. Refractive indices were measured at 298.15 K over the whole composition range for the ethanol (1) + EMISE (2) and water (1) + EMISE (2) binary systems. The results were used to calculate deviations in the refractive index.
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Cites
Influence of chloride, water, and organic solvents on the physical properties of ionic liquids
Seddon, K. R., Stark, A., & Torres, M.-J. (2000) · Pure and Applied Chemistry · doi:10.1351/pac200072122275 · Cited by 2,293
Cited by
Toxicity and biodegradability of imidazolium ionic liquids
Romero, A., Santos, A., Tojo, J., & Rodríguez, A. (2008) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2007.10.079 · Cited by 713
The peculiar effect of water on ionic liquids and deep eutectic solvents
Ma, C., Laaksonen, A., Liu, C., Lu, X., & Ji, X. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00325d · Cited by 584
Leron, R. B., Soriano, A. N., & Li, M.-H. (2012) · Journal of the Taiwan Institute of Chemical Engineers · doi:10.1016/j.jtice.2012.01.007 · Cited by 311
Gardas, R. L., & Coutinho, J. A. P. (2009) · AIChE Journal · doi:10.1002/aic.11737 · Cited by 305
Metadata
- Authors
- Gómez, E., González, B., Calvar, N., Tojo, E., & Domínguez, Á.
- Venue
- Journal of Chemical & Engineering Data
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-08-31
- Volume
- 51
- Issue
- 6
- Pages
- 2096-2102
- ISSN
- 0021-9568 (ISSN-L)
- 1520-5134
- OpenAlex
- W2088736300
- Cited by
- 362
- References
- 1
- FWCI
- 25.79
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gómez, E., González, B., Calvar, N., Tojo, E., & Domínguez, Á. (2006). Physical Properties of Pure 1-Ethyl-3-methylimidazolium Ethylsulfate and Its Binary Mixtures with Ethanol and Water at Several Temperatures. Journal of Chemical & Engineering Data. https://doi.org/10.1021/je060228n
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
