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Partition Coefficients of Organic Compounds in New Imidazolium and Tetralkylammonium Based Ionic Liquids Using Inverse Gas Chromatography

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Mutelet, Fabrice, Revelli, Anne-Laure, Jaubert, Jean-Noël, Sprunger, Laura M., Acree, William E., Baker, Gary A.·2010·Journal of Chemical & Engineering Data

Abstract

Partition coefficients of 51 organic compounds in two ionic liquids (IL), 1-ethyl-3-methylimidazolium dicyanamide and trimethylhexylammonium bis((trifluoromethyl)sulfonyl)amide, were measured using inverse gas chromatography from (322.5 to 352.5) K. These partition coefficients were converted into water-to-IL partition coefficients using the corresponding gas-to-water partition coefficients. Both sets of partition coefficients were analyzed using the Abraham solvation parameter model with cation-specific and anion-specific equation coefficients. The derived equations correlated the experimental gas-to-IL and water-to-IL partition coefficient data to within (0.12 and 0.14) log units, respectively.

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Authors
Mutelet, F., Revelli, A.-L., Jaubert, J.-N., Sprunger, L. M., Acree, W. E., & Baker, G. A.
Venue
Journal of Chemical & Engineering Data
Published
2009-09-11
Volume
55
Issue
1
Pages
234-242
ISSN
  • 0021-9568 (ISSN-L)
  • 1520-5134
OpenAlex
W2070132204
Cited by
160
References
0
FWCI
6.55
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Partition Coefficients of Organic Compounds in New Imidazolium and Tetralkylammonium Based Ionic Liquids Using Inverse Gas Chromatography. https://app.cochat.ai/papers/10.1021/je9003178
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Mutelet, F., Revelli, A.-L., Jaubert, J.-N., Sprunger, L. M., Acree, W. E., & Baker, G. A. (2010). Partition Coefficients of Organic Compounds in New Imidazolium and Tetralkylammonium Based Ionic Liquids Using Inverse Gas Chromatography. Journal of Chemical & Engineering Data. https://doi.org/10.1021/je9003178

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