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Linear solvation energy relationships. 23. A comprehensive collection of the solvatochromic parameters, .pi.*, .alpha., and .beta., and some methods for simplifying the generalized solvatochromic equation
Abstract
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTLinear solvation energy relationships. 23. A comprehensive collection of the solvatochromic parameters, .pi.*, .alpha., and .beta., and some methods for simplifying the generalized solvatochromic equationMortimer J. Kamlet, Jose Luis M. Abboud, Michael H. Abraham, and R. W. TaftCite this: J. Org. Chem. 1983, 48, 17, 2877–2887Publication Date (Print):August 1, 1983Publication History Published online1 May 2002Published inissue 1 August 1983https://pubs.acs.org/doi/10.1021/jo00165a018https://doi.org/10.1021/jo00165a018research-articleACS PublicationsRequest reuse permissionsArticle Views10808Altmetric-Citations3065LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd…
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The increased H-bond acidity and decreased H-bond basicity of fluorinated alcohols can be explained by the electron-withdrawing effect of F on the −OH group.
“The increased H-bond acidity and decreased H-bond basicity of fluorinated alcohols such as 2,2,2-trifluoroethanol and 1,1,1,3,3,3-hexafluoropropan-2-ol have long been known31,32 and can be explained by the electron-withdrawing effect of F on the −OH group.”
From Intermolecular Interactions, Solute Descriptors, and Partition Properties of Neutral Per- and Polyfluoroalkyl Substances (PFAS) (2023) · cites this paper as [31]
The increased H-bond acidity and decreased H-bond basicity of fluorinated alcohols such as 2,2,2-trifluoroethanol and 1,1,1,3,3,3-hexafluoropropan-2-ol have long been known.
“The increased H-bond acidity and decreased H-bond basicity of fluorinated alcohols such as 2,2,2-trifluoroethanol and 1,1,1,3,3,3-hexafluoropropan-2-ol have long been known31,32”
From Intermolecular Interactions, Solute Descriptors, and Partition Properties of Neutral Per- and Polyfluoroalkyl Substances (PFAS) (2023) · cites this paper as [31]
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Migliolo, L., Silva, O. N., Silva, P. A., Costa, M. P., Costa, C. R., Nolasco, D. O., Barbosa, J. A. R. G., Silva, M. R. R., Bemquerer, M. P., Lima, L. M. P., et al. (2012) · PLoS ONE · doi:10.1371/journal.pone.0047047 · Cited by 48
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Metadata
- Authors
- Kamlet, M. J., Abboud, J. L. M., Abraham, M. H., & Taft, R. W.
- Venue
- The Journal of Organic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1983-08
- Volume
- 48
- Issue
- 17
- Pages
- 2877-2887
- ISSN
- 0022-3263
- 1520-6904
- Cited by
- 3,428
- References
- 0
- Language
- en
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