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New Hg2+-Selective Chromo- and Fluoroionophore Based upon 8-Hydroxyquinoline
Abstract
A new 8-hydroxyquinoline derivative having an appended boron-dipyrromethene function has been prepared, and its metal ion sensing properties were investigated. The designed compound exhibited pronounced Hg(2+)-selective on-off-type fluoroionophoric properties among the representative transition- and heavy-metal ions in aqueous dioxane solution. The fluorescence was efficiently quenched more than 98% with 5 equiv of Hg(2+) ions, and the detection limit was found to be 5 x 10(-)(6) M in a dioxane-water (1:3, v/v) solvent system. The ionophore also showed a selective chromogenic behavior toward Hg(2+) ions by changing the color of the solution from light amber to red, which can be detected with the naked eye.
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Citations
Cited by
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Ulrich, G., Ziessel, R., & Harriman, A. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200702070 · Cited by 3,161
Lee, J., Han, M. S., & Mirkin, C. A. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200700269 · Cited by 1,308
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Callan, J. F., de Silva, A. P., & Magri, D. C. (2005) · Tetrahedron · doi:10.1016/j.tet.2005.05.043 · Cited by 1,123
Ros‐Lis, J. V., Marcos, M. D., Mártinez‐Máñez, R., Rurack, K., & Soto, J. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200500583 · Cited by 355
Metadata
- Authors
- Moon, S. Y., Cha, N. R., Kim, Y. H., & Chang, S.-K.
- Venue
- The Journal of Organic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-12-09
- Volume
- 69
- Issue
- 1
- Pages
- 181-183
- ISSN
- 0022-3263 (ISSN-L)
- 1520-6904
- OpenAlex
- W1984505177
- Cited by
- 249
- References
- 0
- FWCI
- 7.27
- Type
- journal article
- Language
- en
- Open access
- closed
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