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Trifluoromethylation of Alkenes by Visible Light Photoredox Catalysis
Abstract
A method for trifluoromethylation of alkenes has been developed employing visible light photoredox catalysis with CF(3)I, Ru(Phen)(3)Cl(2), and DBU. This process works especially well for terminal alkenes to give alkenyl-CF(3) products with only E-stereochemistry. The mild reaction conditions enable the trifluoromethylation of a range of alkenes that bear various functional groups.
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Citations
Cited by
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Tang, X.-J., Thomoson, C. S., & Dolbier, W. R. (2014) · Organic Letters · doi:10.1021/ol502163f · Cited by 323
Recent advances in photoinduced trifluoromethylation and difluoroalkylation
Pan, X., Xia, H., & Wu, J. (2016) · Organic Chemistry Frontiers · doi:10.1039/c6qo00153j · Cited by 283
Metadata
- Authors
- Iqbal, N., Choi, S., Kim, E., & Cho, E. J.
- Venue
- The Journal of Organic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-11-30
- Volume
- 77
- Issue
- 24
- Pages
- 11383-11387
- ISSN
- 0022-3263 (ISSN-L)
- 1520-6904
- OpenAlex
- W2334874989
- Cited by
- 234
- References
- 0
- FWCI
- 14.14
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Trifluoromethylation of Alkenes by Visible Light Photoredox Catalysis. https://app.cochat.ai/papers/10.1021/jo3022346
- The paper
- Iqbal, N., Choi, S., Kim, E., & Cho, E. J. (2012). Trifluoromethylation of Alkenes by Visible Light Photoredox Catalysis. The Journal of Organic Chemistry. https://doi.org/10.1021/jo3022346
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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