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Supramolecular Structures of J-Aggregates of Carbocyanine Dyes in Solution

von Berlepsch, H., Böttcher, C., Ouart, A., Burger, C., Dähne, S., Kirstein, S.·2000·The Journal of Physical Chemistry B

Abstract

Light- and small-angle neutron scattering as well as cryo-transmission electron microscopy (cryo-TEM) studies were performed to probe the structure of J -aggregates formed by a series of achiral dye molecules of the 5,5‘,6,6‘-tetrachlorobenzimidacarbocyanine chromophore having 1,1‘-dialkyl substituents combined with 3,3‘-bis(4-sulfobutyl)-3,3‘-bis(4-carboxybutyl) or 3,3‘-bis(3-carboxypropyl) substituents. Assemblies that display a dependence on the substituents different complex supramolecular structures of nanometer-to-micrometer size have been directly visualized by cryo-TEM. The superstructures span from monomolecular layers formed by the 1,1‘-diethyl-3,3‘-bis(4-sulfobutyl) derivative and stacks of bilayer ribbons in the case of the 1,1‘-dioctyl-3,3‘-bis(4-carboxybutyl) derivative to twisted ropelike structures for the chiral aggregate of the 1,1‘-dioctyl-3,3‘-bis(3-carboxypropyl)-substituted chromophore.

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Metadata

Authors
von Berlepsch, H., Böttcher, C., Ouart, A., Burger, C., Dähne, S., & Kirstein, S.
Venue
The Journal of Physical Chemistry B
Published
2000-05-16
Volume
104
Issue
22
Pages
5255-5262
ISSN
  • 1520-5207 (ISSN-L)
  • 1520-6106
OpenAlex
W1981384569
Cited by
206
References
0
FWCI
9.06
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Supramolecular Structures of J-Aggregates of Carbocyanine Dyes in Solution. https://app.cochat.ai/papers/10.1021/jp000220z
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von Berlepsch, H., Böttcher, C., Ouart, A., Burger, C., Dähne, S., & Kirstein, S. (2000). Supramolecular Structures of J-Aggregates of Carbocyanine Dyes in Solution. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp000220z

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