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Surface Reconstruction of the Unstable {110} Surface in Gold Nanorods
Abstract
Gold nanorods prepared electrochemically and capped in micelles are examined using high-resolution transmission electron microscopy (TEM). It is found that they have an axial growth direction of [001] and have surfaces made of {100} and the unstable {110} facets. A detailed examination of the defect sites of both of these facets shows that while the defective regions of the stable {100} facets show atom-height steps with no reconstruction, the less stable higher energy {110} surfaces show missing-row reconstruction. The role of micelles in stabilizing the {110} facet in the gold nanorod is briefly discussed.
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Cited by
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Xia, Y., Xiong, Y., Lim, B., & Skrabalak, S. E. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200802248 · Cited by 5,702
Gold Nanorods: From Synthesis and Properties to Biological and Biomedical Applications
Huang, X., Neretina, S., & El‐Sayed, M. A. (2009) · Advanced Materials · doi:10.1002/adma.200802789 · Cited by 1,921
Self-citationAnisotropic Gold Nanoparticles: Synthesis, Properties, Applications, and Toxicity
Li, N., Zhao, P., & Astruc, D. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201300441 · Cited by 962
Colloidal Gold and Silver Triangular Nanoprisms
Millstone, J. E., Hurst, S. J., Métraux, G. S., Cutler, J. I., & Mirkin, C. A. (2009) · Small · doi:10.1002/smll.200801480 · Cited by 895
Synthesis and Mechanistic Study of Palladium Nanobars and Nanorods
Xiong, Y., Cai, H., Wiley, B. J., Wang, J., Kim, M. J., & Xia, Y. (2007) · Journal of the American Chemical Society · doi:10.1021/ja0688023 · Cited by 593
Metadata
- Authors
- Wang, Z. L., Gao, R. P., Nikoobakht, B., & El-Sayed, M. A.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-05-16
- Volume
- 104
- Issue
- 23
- Pages
- 5417-5420
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W1971469797
- Cited by
- 249
- References
- 0
- FWCI
- 5.34
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, Z. L., Gao, R. P., Nikoobakht, B., & El-Sayed, M. A. (2000). Surface Reconstruction of the Unstable {110} Surface in Gold Nanorods. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp000800w
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