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Silver Nanoshells: Variations in Morphologies and Optical Properties
Abstract
The production of silica core-silver shell nanoparticles (silver nanoshells) by three different chemical methods is described. Each method produces a silver outer layer with a unique morphology, ranging from smooth and uniform, to rough on the 2−5 nm length scale, to spiky with extremely sharp, needlelike protrusions extending outward from the surface of the nanoparticle. The nanoshells produced by each growth method were studied using transmission electron microscopy and UV−vis spectroscopy. In particular, one reduction method produced silver nanoshells with smooth and highly uniform morphologies whose optical extinction corresponded quantitatively to Mie scattering theory for a silica core-silver shell nanostructure.
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Citations
Cites
Optical Constants of the Noble Metals
Johnson, P. B., & Christy, R. W. (1972) · Physical Review B · doi:10.1103/physrevb.6.4370 · Cited by 20,094
Beiträge zur Optik trüber Medien, speziell kolloidaler Metallösungen
Mie, G. (1908) · Annalen der Physik · doi:10.1002/andp.19083300302 · Cited by 11,537
Cited by
Tailoring Surface Plasmons through the Morphology and Assembly of Metal Nanoparticles
Liz-Marzán, L. M. (2006) · Langmuir · doi:10.1021/la0513353 · Cited by 1,645
Shape‐Controlled Synthesis of Metal Nanostructures: The Case of Silver
Wiley, B., Sun, Y., Mayers, B., & Xia, Y. (2005) · Chemistry – A European Journal · doi:10.1002/chem.200400927 · Cited by 1,643
Self‐Assembled Photonic Structures
Galisteo‐López, J. F., Ibisate, M., Sapienza, R., Froufe‐Pérez, L. S., Blanco, Á., & López, C. (2011) · Advanced Materials · doi:10.1002/adma.201000356 · Cited by 668
Synthesis and Optical Properties of Anisotropic Metal Nanoparticles
Hao, E., Schatz, G. C., & Hupp, J. T. (2004) · Journal of Fluorescence · doi:10.1023/b:jofl.0000031815.71450.74 · Cited by 312
Metadata
- Authors
- Jackson, J. B., & Halas, N. J.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-03-16
- Volume
- 105
- Issue
- 14
- Pages
- 2743-2746
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2064169997
- Cited by
- 498
- References
- 2
- FWCI
- 16.27
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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