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High-Yield Purification Process of Singlewalled Carbon Nanotubes
Abstract
Reproducible high-yield purification process of singlewalled carbon nanotubes was developed by combining two-step processes of thermal annealing in air and acid treatment. The process involves the thermal annealing in air with the powders rotated at temperatures of 470 °C for 50 min, which burns out the carbonaceous particles, and an acid treatment with HCl for 24 h, which etches away the catalytic metals. Control of the annealing temperature and rotation of the sample are crucial for high yield. Our reproducible optimal purification process provides a total yield of about 25 ∼ 30 wt % with less than 1 wt % of transition metals, which was confirmed by the thermogravimetric analysis. Bundling and length control depending on the different acid treatments will be further discussed.
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Citations
Cited by
Carbon Nanotube−Inorganic Hybrids
Eder, D. (2010) · Chemical Reviews · doi:10.1021/cr800433k · Cited by 819
Zhang, Q., Huang, J., Qian, W., Zhang, Y., & Wei, F. (2013) · Small · doi:10.1002/smll.201203252 · Cited by 759
Electrophoretic deposition of carbon nanotubes
Boccaccini, A. R., Cho, J., Roether, J. A., Thomas, B. J. C., Jane Minay, E., & Shaffer, M. S. P. (2006) · Carbon · doi:10.1016/j.carbon.2006.06.021 · Cited by 678
Dispersion of Carbon Nanotubes in Liquids
Hilding, J., Grulke, E. A., George Zhang, Z., & Lockwood, F. (2003) · Journal of Dispersion Science and Technology · doi:10.1081/dis-120017941 · Cited by 668
Carbon nanotubes, science and technology part (I) structure, synthesis and characterisation
Aqel, A., El-Nour, K. M. M. A., Ammar, R. A. A., & Al-Warthan, A. (2012) · Arabian Journal of Chemistry · doi:10.1016/j.arabjc.2010.08.022 · Cited by 615
Purification of Single-Wall Carbon Nanotubes by Electrochemical Oxidation
Fang, H.-T., Liu, C.-G., Liu, C., Li, F., Liu, M., & Cheng, H.-M. (2004) · Chemistry of Materials · doi:10.1021/cm035263h · Cited by 165
Metadata
- Authors
- Moon, J.-M., An, K. H., Lee, Y. H., Park, Y. S., Bae, D. J., & Park, G.-S.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-05-26
- Volume
- 105
- Issue
- 24
- Pages
- 5677-5681
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W1984250391
- Cited by
- 274
- References
- 0
- FWCI
- 11.05
- Type
- journal article
- Language
- en
- Open access
- closed
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