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Synthetic Control of the Diameter and Length of Single Crystal Semiconductor Nanowires
Abstract
A general synthetic method has been developed to control both the diameter and the length of nanowires during growth. This approach exploits monodisperse nanocluster catalysts to define both the nanowire diameter and the initiation of nanowire elongation during growth by a vapor−liquid−solid mechanism. To demonstrate this new approach, crystalline indium phosphide (InP) nanowires have been synthesized using a laser catalytic growth (LCG) process combined with gold nanocluster catalysts. InP nanowires with nearly monodisperse diameters of 10, 20, and 30 nm were grown from nanocluster catalysts having diameters of 10, 20, and 30 nm, respectively. High-resolution transmission electron microscopy studies show that the InP nanowires prepared in this manner are single crystals with a [111] growth direction. In addition, studies of nanowire growth as a function of growth time have shown that nanowire length is directly proportional to growth time and have enabled the preparation of InP nanowires with narrow length distributions centered at 2, 4, 6, and 9 μm. The new level of synthetic control afforded by our approach should enable better-defined fundamental studies of nanowires and open up new opportunities for the assembly of functional nanodevices.
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Cited by
Growth of nanowire superlattice structures for nanoscale photonics and electronics
Gudiksen, M. S., Lauhon, L. J., Wang, J., Smith, D. C., & Lieber, C. M. (2002) · Nature · doi:10.1038/415617a · Cited by 2,709
Self-citationNanowire electronic and optoelectronic devices
Li, Y., Qian, F., Xiang, J., & Lieber, C. M. (2006) · Materials Today · doi:10.1016/s1369-7021(06)71650-9 · Cited by 1,376
Self-citationControlled Growth and Structures of Molecular-Scale Silicon Nanowires
Wu, Y., Cui, Y., Huynh, L., Barrelet, C. J., Bell, D. C., & Lieber, C. M. (2004) · Nano Letters · doi:10.1021/nl035162i · Cited by 963
Self-citationHydrothermal Synthesis of α-MoO3Nanorods via Acidification of Ammonium Heptamolybdate Tetrahydrate
Lou, X. W., & Zeng, H. C. (2002) · Chemistry of Materials · doi:10.1021/cm0206237 · Cited by 377
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Duan, X., Huang, Y., & Lieber, C. M. (2002) · Nano Letters · doi:10.1021/nl025532n · Cited by 346
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Metadata
- Authors
- Gudiksen, M. S., Wang, J., & Lieber, C. M.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-04-18
- Volume
- 105
- Issue
- 19
- Pages
- 4062-4064
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2027006268
- Cited by
- 271
- References
- 0
- FWCI
- 18.80
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gudiksen, M. S., Wang, J., & Lieber, C. M. (2001). Synthetic Control of the Diameter and Length of Single Crystal Semiconductor Nanowires. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp010540y
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