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New Photocatalyst Group for Water Decomposition of RuO2-Loaded p-Block Metal (In, Sn, and Sb) Oxides with d10 Configuration
Abstract
For the decomposition of pure water to hydrogen and oxygen, MIn 2 O 4 (M = Ca, Sr), Sr 2 SnO 4, and NaSbO 3 were found to make stable photocatalysts when combined with RuO 2 . The metal oxides are composed of the d 10 p-block metal ions (In 3+, Sn 4+, and Sb 5+ ), and it is demonstrated that the p-block metal oxides with d 10 configuration form a new photocatalyst group different from the conventional metal oxide photocatalyst group consisting of the octahedrally coordinated d 0 transition-metal ions such as Ti 4+, Zr 4+, Nb 5+, and Ta 5+ .
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Citations
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Maeda, K., Teramura, K., Lu, D., Saito, N., Inoue, Y., & Domen, K. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200602473 · Cited by 641
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Sato, J., Kobayashi, H., Ikarashi, K., Saito, N., Nishiyama, H., & Inoue, Y. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp0373189 · Cited by 320
Self-citationHOU, Y., WU, L., WANG, X., DING, Z., LI, Z., & FU, X. (2007) · Journal of Catalysis · doi:10.1016/j.jcat.2007.05.012 · Cited by 285
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Metadata
- Authors
- Sato, J., Saito, N., Nishiyama, H., & Inoue, Y.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-06-13
- Volume
- 105
- Issue
- 26
- Pages
- 6061-6063
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2007598092
- Cited by
- 213
- References
- 0
- FWCI
- 5.52
- Type
- journal article
- Language
- en
- Open access
- closed
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