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Cited by 220

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A Novel Method for Incorporation of Heteroatoms into the Framework of Ordered Mesoporous Silica Materials Synthesized in Strong Acidic Media

Han, Yu, Xiao, Feng-Shou, Wu, Shuo, Sun, Yinyong, Meng, Xiangju, Li, Dongsheng, Lin, Sen, Deng, Feng, Ai, Xuanjun·2001·The Journal of Physical Chemistry B

Abstract

Heteroatoms of Al and Ti are effectively introduced into the framework of ordered mesoporous silica materials (designated as MAS-7 and MTS-9, respectively) in strong acidic media (pH < 0) by a two-step procedure. MAS-7 shows high catalytic activities for the cracking of both small (cumene) and bulky (1,3,5-tri-isopropylbenzene) molecules because it combines the advantages of both zeolites (strong acidity) and mesoporous materials (large pores). In contrast, Al-SBA-15 samples prepared from both “post-synthesis” and “direct synthesis” present much lower catalytic activities than MAS-7. Furthermore, MTS-9 exhibits very high catalytic activity in phenol hydroxylation by H 2 O 2, giving the phenol conversion of 26%, comparable to TS-1.

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Metadata

Authors
Han, Y., Xiao, F.-S., Wu, S., Sun, Y., Meng, X., Li, D., Lin, S., Deng, F., & Ai, X.
Venue
The Journal of Physical Chemistry B
Published
2001-07-26
Volume
105
Issue
33
Pages
7963-7966
ISSN
  • 1520-5207 (ISSN-L)
  • 1520-6106
OpenAlex
W2041992226
Cited by
220
References
1
FWCI
11.59
Type
journal article
Language
en
Open access
closed

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