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Anomalously Large Equilibrium Clusters of Colloids
Abstract
We propose a mechanism for mesophase separation in a system of aggregating colloids. Conditions are outlined under which colloids can form equilibrium clusters with very large sizes, i.e., aggregation numbers of a thousand or more. The driving force for clustering is a short range attractive interaction which will be treated within a capillarity approximation. The stabilizing mechanism is a small amount of charge per particle. Under the appropriate conditions these charges will interact with unscreened Coulomb potentials and, consequently, prevent large-scale phase separation.
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Citations
Cites
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Entropy-induced dispersion of bulk liquids
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Length Scale for Configurational Entropy in Microemulsions
Reiss, H., Kegel, W. K., & Groenewold, J. (1996) · Berichte der Bunsengesellschaft für physikalische Chemie · doi:10.1002/bbpc.19961000314 · Cited by 32
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Cited by
Equilibrium cluster formation in concentrated protein solutions and colloids
Stradner, A., Sedgwick, H., Cardinaux, F., Poon, W. C. K., Egelhaaf, S. U., & Schurtenberger, P. (2004) · Nature · doi:10.1038/nature03109 · Cited by 1,070
Habraken, W. J. E. M., Tao, J., Brylka, L. J., Friedrich, H., Bertinetti, L., Schenk, A. S., Verch, A., Dmitrovic, V., Bomans, P. H. H., Frederik, P. M., et al. (2013) · Nature Communications · doi:10.1038/ncomms2490 · Cited by 821
The two-step mechanism of nucleation of crystals in solution
Vekilov, P. G. (2010) · Nanoscale · doi:10.1039/c0nr00628a · Cited by 674
Supracolloidal Reaction Kinetics of Janus Spheres
Chen, Q., Whitmer, J. K., Jiang, S., Bae, S. C., Luijten, E., & Granick, S. (2011) · Science · doi:10.1126/science.1197451 · Cited by 526
Sciortino, F., Mossa, S., Zaccarelli, E., & Tartaglia, P. (2004) · Physical Review Letters · doi:10.1103/physrevlett.93.055701 · Cited by 502
Complexation and coacervation of polyelectrolytes with oppositely charged colloids
Kizilay, E., Kayitmazer, A. B., & Dubin, P. L. (2011) · Advances in Colloid and Interface Science · doi:10.1016/j.cis.2011.06.006 · Cited by 408
Ball, V., Frari, D. D., Toniazzo, V., & Ruch, D. (2012) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2012.07.030 · Cited by 404
Confocal microscopy of colloids
Prasad, V, Semwogerere, D., & Weeks, E. R. (2007) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/19/11/113102 · Cited by 310
Interfacial behavior of asphaltenes
Langevin, D., & Argillier, J.-F. (2016) · Advances in Colloid and Interface Science · doi:10.1016/j.cis.2015.10.005 · Cited by 259
Metadata
- Authors
- Groenewold, J., & Kegel, W. K.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-10-05
- Volume
- 105
- Issue
- 47
- Pages
- 11702-11709
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W1963972730
- Cited by
- 265
- References
- 5
- FWCI
- 3.56
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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