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A Microscopic and Spectroscopic Study of Interactions between Carbon Nanotubes and a Conjugated Polymer

McCarthy, B., Coleman, J. N., Czerw, R., Dalton, A. B., in het Panhuis, M., Maiti, A., Drury, A., Bernier, P., Nagy, J. B., Lahr, B., Byrne, H. J., Carroll, D. L., Blau, W. J.·2002·The Journal of Physical Chemistry B

Abstract

Production of stable polymer−nanotube composites depends on good wetting interaction between polymer and nanotube, which is polymer specific, and depends in particular on chain conformation. In this paper, we examine this interaction for a conjugated, semiconducting polymer by a range of microscopic and spectroscopic techniques, to gain a greater understanding of the binding. Several interesting effects are observed, including an order to the interaction between the polymer and nanotube, the tendency of defects in the nanotube structure to nucleate crystal growth, and substantial changes in the spectroscopic behavior of the polymer due to the effect of the nanotubes on polymer conformation. This is substantiated by computational modeling, which demonstrates that these conformational modifications are due to the interaction with the nanotubes.

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Authors
McCarthy, B., Coleman, J. N., Czerw, R., Dalton, A. B., in het Panhuis, M., Maiti, A., Drury, A., Bernier, P., Nagy, J. B., Lahr, B., Byrne, H. J., Carroll, D. L., & Blau, W. J.
Venue
The Journal of Physical Chemistry B
Published
2002-02-08
Volume
106
Issue
9
Pages
2210-2216
ISSN
  • 1520-5207 (ISSN-L)
  • 1520-6106
OpenAlex
W2077561850
Cited by
237
References
0
FWCI
13.10
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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