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Influence of Surface Modification on the Acid Site Distribution of HZSM-5

Zheng, Shourong, Heydenrych, Hilton R., Jentys, Andreas, Lercher, Johannes A.·2002·The Journal of Physical Chemistry B

Abstract

Hydroxyl groups located on the external surface and in the pore mouth region of HZSM-5 zeolites with different crystal sizes were modified by chemical liquid deposition (CLD) of tetraethoxysilane (TEOS). The silylation of the acid sites was monitored using NH 3 sorption, IR spectroscopy of the zeolite hydroxyl groups, and adsorption of pyridine and di- tert -butyl-pyridine (DTBPy). Silylation reduced the concentration of Brønsted acid sites, preferentially in the pore mouth region of the zeolites, and led to a blocking of Lewis acid sites. The deactivation of Lewis acid sites was found to occur prior to the reaction with bridging hydroxyl groups and silanol groups. The efficiency of silylation achieved was found to depend on the particle size of the zeolite sample. A multicycle procedure can be used to increase the effects of the modification with TEOS.

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Metadata

Authors
Zheng, S., Heydenrych, H. R., Jentys, A., & Lercher, J. A.
Venue
The Journal of Physical Chemistry B
Published
2002-08-23
Volume
106
Issue
37
Pages
9552-9558
ISSN
  • 1520-5207 (ISSN-L)
  • 1520-6106
OpenAlex
W2054629555
Cited by
267
References
2
FWCI
3.09
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Influence of Surface Modification on the Acid Site Distribution of HZSM-5. https://app.cochat.ai/papers/10.1021/jp014091d
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Zheng, S., Heydenrych, H. R., Jentys, A., & Lercher, J. A. (2002). Influence of Surface Modification on the Acid Site Distribution of HZSM-5. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp014091d

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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