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Influence of Surface Modification on the Acid Site Distribution of HZSM-5
Abstract
Hydroxyl groups located on the external surface and in the pore mouth region of HZSM-5 zeolites with different crystal sizes were modified by chemical liquid deposition (CLD) of tetraethoxysilane (TEOS). The silylation of the acid sites was monitored using NH 3 sorption, IR spectroscopy of the zeolite hydroxyl groups, and adsorption of pyridine and di- tert -butyl-pyridine (DTBPy). Silylation reduced the concentration of Brønsted acid sites, preferentially in the pore mouth region of the zeolites, and led to a blocking of Lewis acid sites. The deactivation of Lewis acid sites was found to occur prior to the reaction with bridging hydroxyl groups and silanol groups. The efficiency of silylation achieved was found to depend on the particle size of the zeolite sample. A multicycle procedure can be used to increase the effects of the modification with TEOS.
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Cites
Emeis, C. A. (1993) · Journal of Catalysis · doi:10.1006/jcat.1993.1145 · Cited by 3,084
Weitkamp, J. (2000) · Solid State Ionics · doi:10.1016/s0167-2738(00)00632-9 · Cited by 973
Cited by
Cheng, K., Zhou, W., Kang, J., He, S., Shi, S., Zhang, Q., Pan, Y., Wen, W., & Wang, Y. (2017) · Chem · doi:10.1016/j.chempr.2017.05.007 · Cited by 533
Tailored crystalline microporous materials by post-synthesis modification
Valtchev, V., Majano, G., Mintova, S., & Pérez-Ramírez, J. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35196j · Cited by 478
Zaera, F. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00905 · Cited by 425
Zhang, J., Qian, W., Kong, C., & Wei, F. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00192 · Cited by 318
Phenomena Affecting Catalytic Reactions at Solid–Liquid Interfaces
Sievers, C., Noda, Y., Qi, L., Albuquerque, E. M., Rioux, R. M., & Scott, S. L. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02532 · Cited by 288
Metadata
- Authors
- Zheng, S., Heydenrych, H. R., Jentys, A., & Lercher, J. A.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-08-23
- Volume
- 106
- Issue
- 37
- Pages
- 9552-9558
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2054629555
- Cited by
- 267
- References
- 2
- FWCI
- 3.09
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zheng, S., Heydenrych, H. R., Jentys, A., & Lercher, J. A. (2002). Influence of Surface Modification on the Acid Site Distribution of HZSM-5. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp014091d
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