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Photoreactions on LaTiO2N under Visible Light Irradiation
Abstract
Photochemical reactions on LaTiO 2 N, a perovskite-type oxynitride, were examined. Under visible-light irradiation (420 nm < λ < 600 nm), LaTiO 2 N reduced H + into H 2 and oxidized H 2 O into O 2 in the presence of a sacrificial electron donor (methanol) or acceptor (Ag + ) by the band gap transition (2.1 eV). Oxidation of water proceeded with little degradation of the oxynitride, whereas partial substitution of Ca 2+ for La 3+ of LaTiO 2 N and modification by IrO 2 colloid markedly suppressed degradation of the oxynitride and increased O 2 evolution efficiency.
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Cited by
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Yang, J., Wang, D., Han, H., & Li, C. (2013) · Accounts of Chemical Research · doi:10.1021/ar300227e · Cited by 2,848
Visible-light driven heterojunction photocatalysts for water splitting – a critical review
Moniz, S. J. A., Shevlin, S. A., Martin, D. J., Guo, Z.-X., & Tang, J. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03271c · Cited by 2,363
Abe, R. (2010) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2011.02.003 · Cited by 1,223
Maeda, K., Teramura, K., Lu, D., Saito, N., Inoue, Y., & Domen, K. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200602473 · Cited by 641
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Metadata
- Authors
- Kasahara, A., Nukumizu, K., Hitoki, G., Takata, T., Kondo, J. N., Hara, M., Kobayashi, H., & Domen, K.
- Venue
- The Journal of Physical Chemistry A
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-06-28
- Volume
- 106
- Issue
- 29
- Pages
- 6750-6753
- ISSN
- 1089-5639 (ISSN-L)
- 1520-5215
- OpenAlex
- W2326845365
- Cited by
- 452
- References
- 0
- FWCI
- 11.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kasahara, A., Nukumizu, K., Hitoki, G., Takata, T., Kondo, J. N., Hara, M., Kobayashi, H., & Domen, K. (2002). Photoreactions on LaTiO2N under Visible Light Irradiation. The Journal of Physical Chemistry A. https://doi.org/10.1021/jp025961%2B
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