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Photocatalytic Activity for Water Decomposition of Indates with Octahedrally Coordinated d10 Configuration. I. Influences of Preparation Conditions on Activity
Abstract
The photocatalytic properties for water decomposition of RuO 2 -dispersed alkaline earth metal and lanthanum indates with an octahedrally coordinated In 3+ ion of d 10 configuration were studied. The influences of preparation methods, calcination temperature, and the amount of RuO 2 on the activity of RuO 2 -dispersed CaIn 2 O 4 were examined, and it was shown that the combination of well-crystallized CaIn 2 O 4 with highly dispersed RuO 2 particles led to high photocatalytic performance: hydrogen and oxygen were stably produced at nearly the stoichiometric ratio under UV irradiation. The photocatalytic activity of RuO 2 -dispersed Sr 1 - x Ca x In 2 O 4 ( x = 0.25, 0.50, 0.75) increased monotonically with increasing x . The activity of RuO 2 -dispersed Sr 0.93 Ba 0.07 In 2 O 4 was similar to that of RuO 2 -dispersed SrIn 2 O 4, whereas RuO 2 -dispersed LaInO 3 had much lower activity. The photocatalytic properties of different kinds of indates were compared.
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Photocatalytic Activity for Water Decomposition of RuO2-Dispersed Zn2GeO4 with d10 Configuration
Sato, J., Kobayashi, H., Ikarashi, K., Saito, N., Nishiyama, H., & Inoue, Y. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp0373189 · Cited by 320
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Metadata
- Authors
- Sato, J., Saito, N., Nishiyama, H., & Inoue, Y.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-07-12
- Volume
- 107
- Issue
- 31
- Pages
- 7965-7969
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2012134384
- Cited by
- 159
- References
- 0
- FWCI
- 8.72
- Type
- journal article
- Language
- en
- Open access
- closed
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- Sato, J., Saito, N., Nishiyama, H., & Inoue, Y. (2003). Photocatalytic Activity for Water Decomposition of Indates with Octahedrally Coordinated d10 Configuration. I. Influences of Preparation Conditions on Activity. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp030020y
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