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Preparation and Electrochemical Performance of Polycrystalline and Single Crystalline CuO Nanorods as Anode Materials for Li Ion Battery
Abstract
A simple and efficient approach is developed for the synthesis of copper oxide nanorods with different morphology and crystallographic structure. Polycrystalline fine rods 10−20 nm thick and several hundred nanometers long and single crystalline thick rods 60−100 nm thick and up to 1 μm long were obtained from the reactions of copper hydrate with caustic soda solution at room temperature and 100 °C, respectively. The fine CuO nanorods as anode materials for Li ion battery exhibit a high electrochemical capacity of 766 mA h/g and relatively poor capacity retention as compared to thick nanorods with the single crystalline structure. The correlation between the structural features of the nanorods and their electrode performance is discussed in detail.
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Citations
Cited by
Cabana, J., Monconduit, L., Larcher, D., & Palacín, M. R. (2010) · Advanced Materials · doi:10.1002/adma.201000717 · Cited by 2,361
A Comprehensive Review of Glucose Biosensors Based on Nanostructured Metal-Oxides
Rahman, M. M., Ahammad, A. J. S., Jin, J.-H., Ahn, S. J., & Lee, J.-J. (2010) · Sensors · doi:10.3390/s100504855 · Cited by 762
Multi-electron reaction materials for high energy density batteries
Gao, X.-P., & Yang, H.-X. (2010) · Energy Environ. Sci. · doi:10.1039/b916098a · Cited by 624
Self-citationCopper Oxide/Hydroxide Nanomaterial Synthesized from Simple Copper Salt
Rajani, C., Anuradha, V., & Sunandamma, Y. (2020) · International Journal of Nanoscience · doi:10.1142/s0219581x19500285 · Cited by 7
Metadata
- Authors
- Gao, X. P., Bao, J. L., Pan, G. L., Zhu, H. Y., Huang, P. X., Wu, F., & Song, D. Y.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-04-10
- Volume
- 108
- Issue
- 18
- Pages
- 5547-5551
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2026461849
- Cited by
- 578
- References
- 0
- FWCI
- 13.96
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gao, X. P., Bao, J. L., Pan, G. L., Zhu, H. Y., Huang, P. X., Wu, F., & Song, D. Y. (2004). Preparation and Electrochemical Performance of Polycrystalline and Single Crystalline CuO Nanorods as Anode Materials for Li Ion Battery. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp037075k
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