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Evidence for the Monolayer Assembly of Poly(vinylpyrrolidone) on the Surfaces of Silver Nanowires
Abstract
The well-defined silver (Ag) nanowires with five-twinned structure have been prepared by polyol reduction in the presence of poly(vinylpyrrolidone) (PVP K-30, 40 000). The obtained Ag nanowires are nearly monodispersed with an average diameter of 70 nm and length of 6 μm. It is confirmed from the results of thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), and Fourier transform Raman spectra (FT-Raman) that one monolayer of the PVP molecules might be absorbed on the surface of the Ag nanowires through Ag−O coordination. On the basis of the experimental analysis, the probable spatial conformation of the PVP molecules is supposed to be that the CH skeleton chain of the PVP is close to the surface of the Ag nanowires. The pyrrolidone ring might be tilted on the surface of the Ag nanowires through Ag:O coordination. These results may provide direct evidence for the role of the PVP molecules in the formation of the Ag nanowires.
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Cites
Shape control of CdSe nanocrystals
Peng, X., Manna, L., Yang, W., Wickham, J., Scher, E., Kadavanich, A., & Alivisatos, A. P. (2000) · Nature · doi:10.1038/35003535 · Cited by 4,487
Transmission Electron Microscopy of Shape-Controlled Nanocrystals and Their Assemblies
Wang, Z. L. (2000) · The Journal of Physical Chemistry B · doi:10.1021/jp993593c · Cited by 2,137
Cited by
Shape‐Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics?
Xia, Y., Xiong, Y., Lim, B., & Skrabalak, S. E. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200802248 · Cited by 5,702
Shen, Y., Lin, Y. H., & Nan, C. ‐. (2007) · Advanced Functional Materials · doi:10.1002/adfm.200700200 · Cited by 294
Metadata
- Authors
- Gao, Y., Jiang, P., Liu, D. F., Yuan, H. J., Yan, X. Q., Zhou, Z. P., Wang, J. X., Song, L., Liu, L. F., Zhou, W. Y., Wang, G., Wang, C. Y., Xie, S. S., Zhang, J. M., & Shen, D. Y.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-07-09
- Volume
- 108
- Issue
- 34
- Pages
- 12877-12881
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W1989024003
- Cited by
- 279
- References
- 2
- FWCI
- 7.61
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gao, Y., Jiang, P., Liu, D. F., Yuan, H. J., Yan, X. Q., Zhou, Z. P., Wang, J. X., Song, L., Liu, L. F., Zhou, W. Y., Wang, G., Wang, C. Y., Xie, S. S., Zhang, J. M., & Shen, D. Y. (2004). Evidence for the Monolayer Assembly of Poly(vinylpyrrolidone) on the Surfaces of Silver Nanowires. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp037116c
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