The DOI matches its Crossref record; 23 of the 23 references it cites were found in a registry or an index.
In-Situ ATR-FTIR Spectroscopic Study of Electro-oxidation of Methanol and Adsorbed CO at Pt−Ru Alloy
Abstract
Methanol oxidation reaction (MOR) has been investigated at sputtered Pt−Ru, Ru, and Pt electrodes by using in-situ FTIR spectroscopy with the attenuated total reflection technique (ATR), which can identify species adsorbed on the electrode surface. Linear CO, bridged CO, and COO - were detected as the intermediates in the MOR. The electro-oxidation of preadsorbed CO was also studied to clarify the mechanism of the MOR at these electrodes. Water molecules coadsorbed with CO were clearly detected at Pt−Ru and Ru electrodes at less positive potential region below the onset potential of ca. 400 mV vs RHE for the electro-oxidation of both methanol and preadsorbed CO. The IR-band intensities of both the adsorbed CO and water commenced to decrease simultaneously at ca. 400 mV on Pt−Ru alloy, demonstrating that the adsorbed CO is oxidized by consuming the adsorbed water. The pure Ru electrode exhibited a high activity for the oxidation of preadsorbed CO, but showed a low activity for the MOR due to the slow dehydrogenation adsorption of the methanol. It is clarified that Pt sites on the alloy surface dehydrogenate methanol and form CO dominantly while Ru sites adsorb water molecules preferentially as oxygen-species needed for the CO oxidation, presumably involved as Ru−OH formed by discharging the adsorbed water. These results support the “bifunctional mechanism” at Pt−Ru alloy for the oxidation of methanol and CO.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Effects of Configuration Interaction on Intensities and Phase Shifts
Fano, U. (1961) · Physical Review · doi:10.1103/physrev.124.1866 · Cited by 11,165
DMFCs: From Fundamental Aspects to Technology Development
Aricò, A. S., Srinivasan, S., & Antonucci, V. (2001) · Fuel Cells · doi:10.1002/1615-6854(200107)1:2<133::aid-fuce133>3.0.co;2-5 · Cited by 1,464
Watanabe, M., & Motoo, S. (1975) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/s0022-0728(75)80261-0 · Cited by 1,263
Self-citationThe oxidation of small organic molecules
Parsons, R., & VanderNoot, T. (1988) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/0022-0728(88)87028-1 · Cited by 1,207
Ataka, K.-I., Yotsuyanagi, T., & Osawa, M. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp953636z · Cited by 895
Watanabe, M., & Motoo, S. (1975) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/s0022-0728(75)80262-2 · Cited by 821
Self-citationOsawa, M. (1997) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.70.2861 · Cited by 691
Temperature‐Dependent Methanol Electro‐Oxidation on Well‐Characterized Pt‐Ru Alloys
Gasteiger, H. A., Marković, N., Ross, P. N., & Cairns, E. J. (1994) · Journal of The Electrochemical Society · doi:10.1149/1.2055007 · Cited by 585
High Performance Direct Methanol Polymer Electrolyte Fuel Cells
Ren, X., Wilson, M. S., & Gottesfeld, S. (1996) · Journal of The Electrochemical Society · doi:10.1149/1.1836375 · Cited by 575
Formate, an Active Intermediate for Direct Oxidation of Methanol on Pt Electrode
Chen, Y. X., Miki, A., Ye, S., Sakai, H., & Osawa, M. (2003) · Journal of the American Chemical Society · doi:10.1021/ja029044t · Cited by 496
Cited by
Yang, W., Su, Z., Xu, Z., Yang, W., Peng, Y., & Li, J. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.118150 · Cited by 746
Circumventing Challenges: Design of Anodic Electrocatalysts for Hybrid Water Electrolysis Systems
Wang, H., Sun, M., Ren, J., & Yuan, Z. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202203568 · Cited by 183
Du, L., Xing, L., Zhang, G., Dubois, M., & Sun, S. (2020) · Small Methods · doi:10.1002/smtd.202000016 · Cited by 91
Yang, F., Ye, J., Gao, L., Yu, J., Yang, Z., Lu, Y., Ma, C., Zeng, Y., & Huang, H. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202301408 · Cited by 79
Liang, L., Xu, K., Liang, J., Ye, S., Zeng, B., Liu, Q., Song, H., Du, L., & Cui, Z. (2024) · Small · doi:10.1002/smll.202403557 · Cited by 10
Metadata
- Authors
- Yajima, T., Uchida, H., & Watanabe, M.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-02-01
- Volume
- 108
- Issue
- 8
- Pages
- 2654-2659
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2004900741
- Cited by
- 347
- References
- 23
- FWCI
- 20.08
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: In-Situ ATR-FTIR Spectroscopic Study of Electro-oxidation of Methanol and Adsorbed CO at Pt−Ru Alloy. https://app.cochat.ai/papers/10.1021/jp037215q
- The paper
- Yajima, T., Uchida, H., & Watanabe, M. (2004). In-Situ ATR-FTIR Spectroscopic Study of Electro-oxidation of Methanol and Adsorbed CO at Pt−Ru Alloy. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp037215q
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
