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Role of Metal Nanoparticles in TiO2/Ag Nanocomposite-Based Microheterogeneous Photocatalysis
Open accessAbstract
The photocatalytic performance of anatase TiO 2 nanorod-stabilized Ag nanoparticles has been investigated during the reductive bleaching of a model dye, Uniblue A (UBA), in homogeneous organic solutions. The activity of the TiO 2 /Ag nanocomposite has been found to vary continuously during the course of photocatalysis, following a concomitant light-induced modification of the metal nanoparticle size and size distribution. The direct involvement of the metal particles in mediating electron transfer between photoexcited TiO 2 and the target UBA is explained on the basis of the size-dependent redox properties of the metal nanoparticles. The present results can be useful in the design of new composite materials with well-tailored photocatalytic properties and long-term stability.
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Cites
Catalytic nanoarchitectures—The importance of nothing and the unimportance of periodicity
Rolison, D. R. (2003) · Science · doi:10.1126/science.1082332 · Cited by 1,037
Cited by
Rauf, M. A., Meetani, M. A., & Hisaindee, S. (2011) · Desalination · doi:10.1016/j.desal.2011.03.071 · Cited by 759
Nanocomposites of TiO2 and Reduced Graphene Oxide as Efficient Photocatalysts for Hydrogen Evolution
Fan, W., Lai, Q., Zhang, Q., & Wang, Y. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp2008804 · Cited by 632
Theoretical Studies of Photoinduced Electron Transfer in Dye-Sensitized TiO2
Duncan, W. R., & Prezhdo, O. V. (2007) · Annual Review of Physical Chemistry · doi:10.1146/annurev.physchem.58.052306.144054 · Cited by 580
Gomathi Devi, L., & Kavitha, R. (2016) · Applied Surface Science · doi:10.1016/j.apsusc.2015.11.016 · Cited by 359
Metadata
- Authors
- Cozzoli, P. D., Fanizza, E., Comparelli, R., Curri, M. L., Agostiano, A., & Laub, D.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-06-05
- Volume
- 108
- Issue
- 28
- Pages
- 9623-9630
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W1970026245
- Cited by
- 202
- References
- 1
- FWCI
- 6.26
- Type
- journal article
- Language
- en
- Open access
- green
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- Cozzoli, P. D., Fanizza, E., Comparelli, R., Curri, M. L., Agostiano, A., & Laub, D. (2004). Role of Metal Nanoparticles in TiO2/Ag Nanocomposite-Based Microheterogeneous Photocatalysis. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp0379751
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