The DOI matches its Crossref record; 52 of the 52 references it cites were found in a registry or an index.
Thin Film Water
Abstract
Thin film water is ubiquitous. It coats insulators, even ice, under ambient conditions. And the film can have a profound effect on the physical and chemical properties of the substrates it covers. The direct measurement of thin film water by infrared spectroscopy is described. Our studies can reveal film thicknesses, hydrogen bonding networks, thermodynamic properties, and molecular orientations. Recent examples of our research, with the focus on two model substrates, NaCl and ice, are discussed.
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“The role of water as both a solvent and a reactant can diverge dramatically from bulk aqueous liquid when confined to nanoscale dimensions (nominally single-digit nm) at or between interfaces.135,136”
From Molecular-scale mechanisms of CO2 mineralization in nanoscale interfacial water films (2022) · cites this paper as [135]
Citations
Cites
The adsorption of gases on plane surfaces of glass, mica and platinum
Langmuir, I. (1918) · Journal of the American Chemical Society · doi:10.1021/ja02242a004 · Cited by 23,242
Handbook of Optical Constants of Solids
(1985) · Elsevier eBooks · doi:10.1016/c2009-0-20920-2 · Cited by 21,174
Physical chemistry of surfaces
Adamson, A. W., & Gast, A. P. (1998) · Choice Reviews Online · doi:10.5860/choice.35-4499 · Cited by 11,685
Intermolecular and Surface Forces
Israelachvili, J. N. (2011) · Elsevier eBooks · doi:10.1016/c2009-0-21560-1 · Cited by 8,241
Capillarity and Wetting Phenomena
de Gennes, P. G., Brochard‐Wyart, F., & Quéré, D. (2004) · Springer eBooks · doi:10.1007/978-0-387-21656-0 · Cited by 3,267
Microphysics of Clouds and Precipitation
Pruppacher, H. R., Klett, J. D., & Wang, P. K. (1998) · Aerosol Science and Technology · doi:10.1080/02786829808965531 · Cited by 2,912
The interaction of water with solid surfaces: Fundamental aspects
Thiel, P. A., & Madey, T. E. (1987) · Surface Science Reports · doi:10.1016/0167-5729(87)90001-x · Cited by 2,411
The interaction of water with solid surfaces: fundamental aspects revisited
Henderson, M. (2002) · Surface Science Reports · doi:10.1016/s0167-5729(01)00020-6 · Cited by 2,297
Optical constants of ice from the ultraviolet to the microwave
Warren, S. G. (1984) · Applied Optics · doi:10.1364/ao.23.001206 · Cited by 1,615
Fletcher, N. H. (1970) · Cambridge University Press eBooks · doi:10.1017/cbo9780511735639 · Cited by 827
Optical constants of water in the infrared
Downing, H. D., & Williams, D. (1975) · Journal of Geophysical Research Atmospheres · doi:10.1029/jc080i012p01656 · Cited by 532
Chemistry of the Natural Atmosphere
(1988) · International geophysics/International geophysics series · doi:10.1016/s0074-6142(08)x6036-x · Cited by 386
Intermolecular Potentials from Crossed-Beam Differential Elastic Scattering Measurements. IV. Ar+Ar
PARSON, J. M., Siska, P. E., & Lee, Y. T. (1972) · The Journal of Chemical Physics · doi:10.1063/1.1677399 · Cited by 323
Measuring the Thickness of the Liquid-like Layer on Ice Surfaces with Atomic Force Microscopy
Döppenschmidt, A., & Butt, H. (2000) · Langmuir · doi:10.1021/la990799w · Cited by 303
Buch, V., Sandler, P., & Sadlej, J. (1998) · The Journal of Physical Chemistry B · doi:10.1021/jp980866f · Cited by 302
Shultz, M. J., Schnitzer, C. S., Simonelli, D., & Baldelli, S. (2000) · International Reviews in Physical Chemistry · doi:10.1080/014423500229882 · Cited by 290
MICROPHYSICS AND HETEROGENEOUS CHEMISTRY OF POLAR STRATOSPHERIC CLOUDS
Peter, T. (1997) · Annual Review of Physical Chemistry · doi:10.1146/annurev.physchem.48.1.785 · Cited by 283
Ellipsometric study of the transition layer on the surface of an ice crystal
Furukawa, Y., Yamamoto, M., & Kuroda, T. (1987) · Journal of Crystal Growth · doi:10.1016/s0022-0248(87)80012-x · Cited by 229
The ice/water interface: A molecular dynamics simulation study
Karim, O. A., & Haymet, A. D. J. (1988) · The Journal of Chemical Physics · doi:10.1063/1.455363 · Cited by 229
Optical study of surface melting on ice
Elbaum, M., Lipson, S. G., & Dash, J. G. (1993) · Journal of Crystal Growth · doi:10.1016/0022-0248(93)90483-d · Cited by 220
Goldberg, S. (1993) · Soil Science · doi:10.1097/00010694-199309000-00010 · Cited by 210
Surface melting of the (0001) face of TIP4P ice
Kroes, G. (1992) · Surface Science · doi:10.1016/0039-6028(92)90809-k · Cited by 176
Transition layer on the surface on ice
Beaglehole, D., & Nason, D. (1980) · Surface Science · doi:10.1016/0039-6028(80)90313-1 · Cited by 173
Infrared Spectra of Large H 2 O Clusters: New Understanding of the Elusive Bending Mode of Ice
Devlin, J. P., Sadlej, J., & Buch, V. (2001) · The Journal of Physical Chemistry A · doi:10.1021/jp003455j · Cited by 163
Possible displacement of the climate signal in ancient ice by premelting and anomalous diffusion
Rempel, A. W., Waddington, E. D., Wettlaufer, J. S., & Worster, M. G. (2001) · Nature · doi:10.1038/35079043 · Cited by 162
Intrinsic surface disorder in ice near the melting point
Golecki, I., & Jaccard, C. (1978) · Journal of Physics C Solid State Physics · doi:10.1088/0022-3719/11/20/018 · Cited by 153
Adsorption of water on the NaCl(001) surface. II. An infrared study at ambient temperatures
Foster, M. C., & Ewing, G. E. (2000) · The Journal of Chemical Physics · doi:10.1063/1.481256 · Cited by 148
Self-citationInadequacy of Lifshitz theory for thin liquid films
Beaglehole, D., Radlińska, E. Z., Ninham, B. W., & Christenson, H. K. (1991) · Physical Review Letters · doi:10.1103/physrevlett.66.2084 · Cited by 137
Water on Salt: An Infrared Study of Adsorbed H2O on NaCl(100) under Ambient Conditions
Peters, S. J., & Ewing, G. E. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp972810b · Cited by 132
Self-citationThin Film Water on Muscovite Mica
Cantrell, & Ewing, G. E. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp004305b · Cited by 118
Self-citationIn Situ Vibrational Spectroscopic Studies of the CaF2/H2O Interface
Becraft, K. A., & Richmond, G. L. (2001) · Langmuir · doi:10.1021/la011133g · Cited by 115
Saliba, N. A., Yang, H., & Finlayson‐Pitts, B. J. (2001) · The Journal of Physical Chemistry A · doi:10.1021/jp012330r · Cited by 112
Structure of water in thin layers
Deryagin, B. V., & Churaev, N. V. (1987) · Langmuir · doi:10.1021/la00077a002 · Cited by 112
Pittenger, B., Fain, S. C., Cochran, M. J., Donev, J. M. K., Robertson, B. E., Szuchmacher, A., & Overney, R. M. (2001) · Physical review. B, Condensed matter · doi:10.1103/physrevb.63.134102 · Cited by 94
Anisotropic Surface Melting of an Ice Crystal and Its Relationship to Growth Forms
Furukawa, Y., & Nada, H. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp9631700 · Cited by 92
Structure of the Ice Nanocrystal Surface from Simulated versus Experimental Spectra of Adsorbed CF4
Buch, V., Delzeit, L. D., Blackledge, C. W., & Devlin, J. P. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp952193w · Cited by 91
A theoretical study of the OH stretching region of the vibrational spectrum of ice Ih
McGraw, R., Madden, W. G., Bergren, M. S., Rice, S. A., & Sceats, M. G. (1978) · The Journal of Chemical Physics · doi:10.1063/1.437081 · Cited by 82
Thin Film Water on NaCl(100) under Ambient Conditions: An Infrared Study
Peters, S. J., & Ewing, G. E. (1997) · Langmuir · doi:10.1021/la970629o · Cited by 77
Self-citationA proposed antiferroelectric structure for proton ordered ice Ih
Davidson, E. R., & Morokuma, K. (1984) · The Journal of Chemical Physics · doi:10.1063/1.448101 · Cited by 69
Gallosilicate zeolite catalysts: structural features of [Si,Ga]-ZSM-5
Liu, X., & Klinowski, J. (1992) · The Journal of Physical Chemistry · doi:10.1021/j100187a041 · Cited by 50
Internal Reflection Spectroscopy
Harrick, N. J., & Kirkpatrick, P. H. (1968) · American Journal of Physics · doi:10.1119/1.1974328 · Cited by 50
Sadtchenko, V., Ewing, G. E., Nutt, D., & Stone, A. J. (2002) · Langmuir · doi:10.1021/la0255370 · Cited by 46
Self-citationAdsorption of water on the NaCl(001) surface. III. Monte Carlo simulations at ambient temperatures
Engkvist, O., & Stone, A. J. (2000) · The Journal of Chemical Physics · doi:10.1063/1.481257 · Cited by 45
Shang, X., Benderskii, A. V., & Eisenthal, K. B. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp0105746 · Cited by 43
A new approach to the study of interfacial melting of ice: infrared spectroscopy
Sadtchenko, V., & Ewing, G. E. (2003) · Canadian Journal of Physics · doi:10.1139/p03-009 · Cited by 40
Self-citationAdsorption of water on NaCl(001). I. Intermolecular potentials and low temperature structures
Engkvist, O., & Stone, A. J. (1999) · The Journal of Chemical Physics · doi:10.1063/1.479144 · Cited by 36
Different modes of water aggregation on (111) surfaces of fluorite structures
Wassermann, B., Reif, J., & Matthias, E. (1994) · Physical review. B, Condensed matter · doi:10.1103/physrevb.50.2593 · Cited by 30
Nucleated deliquescence of salt
Cantrell, W., McCrory, C. C. L., & Ewing, G. E. (2002) · The Journal of Chemical Physics · doi:10.1063/1.1429924 · Cited by 28
Self-citationStructure and Properties of Liquid Water
Orentlicher, M., & Vogelhut, P. O. (1966) · The Journal of Chemical Physics · doi:10.1063/1.1727562 · Cited by 26
Rovere, M. (2004) · Journal of Physics Condensed Matter · doi:10.1088/0953-8984/16/45/e01 · Cited by 8
Attenuated (but Not Total) Internal Reflection FT-IR Spectroscopy of Thin Films
Cantrell, W., & Ewing, G. E. (2002) · Applied Spectroscopy · doi:10.1366/0003702021955240 · Cited by 3
Self-citationInfrared spectroscopy of CO on NaCl(100)
Richardson, H. H., Chang, H., Noda, C., & Ewing, G. E. (1989) · Surface Science Letters · doi:10.1016/0167-2584(89)90866-9 · Cited by 1
Self-citation
Research works printed but not linked: 31
- DeHann D. O., 1999, J. Int. Rev. Phys. Chem., 18, 385
- Kirk-Othmer Encyclopedia of Chemical Technology; Wiley: New York, 2000.
- Tardos G. I., 1996, Powder Handl. Process., 8, 15
- Allen H C, 1996, J. Phys. Chem., 100, 6375
- Faraday M., 1850, June 7
- Dash J. G., 2001, J. Geophys. Res., 106, 203407
- Dash J. G., 1995, Rep. Prog. Phys., 58, 167
- Conklin M. H., 1993, J. Geophys Res., 98, 16858
- Dash J. G., 1999, Rev. Mod. Phys., 71, 1743
- Bruch L. W., 1995, J. Chem. Phys., 1103, 5120
- Derjaguin B. V., 1987, Consultants Bureau: New York
- Shindo H., 1992, J. Chem. Soc., Faraday Trans., 93, 1174
- Hu J., 1995, Science, 268, 269
- Shen Y. R., 1998, Solid State Commun., 108, 406
- Pimentel G. C., 1960, The Hydrogen Bond
- Ikawa S.-I., 1968, Spectrochim. Acta, 24, 665
- Devlin J. P., 1995, J. Phys. Chem., 99, 16548
- Horn A. B., 1992, J. Chem. Soc., Faraday Trans., 88, 1078
- Dai D., 1995, J. Phys. Chem., 99, 10304
- Sadtchenko V., 2002, J. Chem. Phys., 116, 4301
- Zhang Z., 2002, Anal. Chem., 74, 2583
- Sadtchenko V., 2002, J. Chem. Phys., 116, 4697
- Born M., 1998, Principles of Optics
- National Research Council (U.S.) International Critical Tables; McGraw-Hill: New York, 1926.
- Dai Q., 1997, J. Phys. Chem. B, 101, 19989
- Petrenko V. F., 1999, Physics of Ice
- Warren S. G., 1984, Appl. Opt., 23, 1225, 10.1364/ao.23.001206 · DOI
- Al-Abadleh H A, 2003, Langmuir, 19, 8810
- Coulson C. A., 1966, Proc. R. Soc. London, 291, 454
- Matsumoto M., 2002, Nature, 414, 257
- Jorgensen W. L., 1983, J. Am. Chem. Soc., 79, 926
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Metadata
- Authors
- Ewing, G. E.
- Affiliations
- Indiana University Bloomington (US)
- Corresponding author
- Ewing, George E.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-09-16
- Volume
- 108
- Issue
- 41
- Pages
- 15953-15961
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2046340127
- Semantic Scholar
- 9bfa9fdb53d5838aa46d940847ab870000125152
- Cited by
- 112
- References
- 52
- Citations by year
- 2026: 3 · 2025: 3 · 2024: 1 · 2023: 5 · 2022: 5 · 2021: 6 · 2020: 2 · 2019: 4 · 2018: 4 · 2017: 4 · 2016: 2 · 2015: 5 · 2014: 3 · 2013: 7 · 2012: 8
- FWCI
- 5.53
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- The Journal of Physical Chemistry B (publishedVersion)
- Topics
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Spectroscopy and Quantum Chemical Studies
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Biophysics › Chemical and Physical Studies
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › nanoparticles nucleation surface interactions
- Keywords
- ice, sodium chloride, hydrogen bond network, film thickness, molecular orientation
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