The DOI matches its Crossref record; 13 of the 13 references it cites were found in a registry or an index.
Stability of Nanocrystals: Thermodynamic Analysis of Oxidation and Re-reduction of Cobalt in Water/Hydrogen Mixtures
Abstract
The stability of nanosized materials differs significantly from the stability of bulk materials. In this study a thermodynamic analysis on the simultaneous oxidation and re-reduction of small metallic cobalt crystallites in the presence of water and hydrogen as a function of the crystallite diameter was performed as a model for catalyst deactivation in the Fischer-Tropsch synthesis. It is shown that spherical cobalt crystallites with a diameter less than 4.4 nm are likely to be oxidized under realistic Fischer-Tropsch synthesis conditions (p(H)(2)(O)/p(H)(2) < 1.5, T = 493 K).
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Citations
Cites
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Dry, M. E. (2002) · Catalysis Today · doi:10.1016/s0920-5861(01)00453-9 · Cited by 2,061
Self-citation(2005) · Van Nostrand's Encyclopedia of Chemistry · doi:10.1002/0471740039.vec1045 · Cited by 1,497
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Colloidal Nanocrystal Shape and Size Control: The Case of Cobalt
Puntes, V. F., Krishnan, K. M., & Alivisatos, A. P. (2001) · Science · doi:10.1126/science.1058495 · Cited by 869
Structure of Metallic Catalysts
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A Solution-Phase Chemical Approach to a New Crystal Structure of Cobalt
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Size effect on the crystal phase of cobalt fine particles
Kitakami, O., Sato, H., Shimada, Y., Sato, F., & Tanaka, M. (1997) · Physical review. B, Condensed matter · doi:10.1103/physrevb.56.13849 · Cited by 501
Oxidation of cobalt based Fischer–Tropsch catalysts as a deactivation mechanism
van Berge, P. J., van de Loosdrecht, J., Barradas, S., & van der Kraan, A. M. (2000) · Catalysis Today · doi:10.1016/s0920-5861(00)00265-0 · Cited by 285
Cited by
Khodakov, A. Y., Chu, W., & Fongarland, P. (2007) · Chemical Reviews · doi:10.1021/cr050972v · Cited by 2,377
Deactivation of cobalt based Fischer–Tropsch catalysts: A review
Tsakoumis, N. E., Rønning, M., Borg, Ø., Rytter, E., & Holmen, A. (2010) · Catalysis Today · doi:10.1016/j.cattod.2010.02.077 · Cited by 593
Dalai, A. K., & Davis, B. H. (2008) · Applied Catalysis A: General · doi:10.1016/j.apcata.2008.06.021 · Cited by 323
Johny, J., Kamp, M., Prymak, O., Tymoczko, A., Wiedwald, U., Rehbock, C., Schürmann, U., Popescu, R., Gerthsen, D., Kienle, L., et al. (2021) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.1c02138 · Cited by 47
Metadata
- Authors
- van Steen, E., Claeys, M., Dry, M. E., van de Loosdrecht, J., Viljoen, E. L., & Visagie, J. L.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-01-27
- Volume
- 109
- Issue
- 8
- Pages
- 3575-3577
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2080919804
- Cited by
- 300
- References
- 13
- FWCI
- 4.30
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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