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Structure of Ionic Liquid−Benzene Mixtures
Abstract
Neutron diffraction has been used to investigate the structure of liquid mixtures of 1,3-dimethylimidazolium hexafluorophosphate with benzene. Two concentrations of benzene were investigated, namely, 33 mol % and 67 mol %, and show similar structures in each case. The presence of benzene significantly alters the ionic liquid structure, in particular, in the cation-cation interactions, in agreement with the single-crystal structure described recently (Holbrey, J. D.; Reichert, W. M.; Nieuwenhuyzen, M.; Sheppard, O.; Hardacre, C.; Rogers, R. D. Chem. Commun. 2003, 476). In each case, the data was analyzed using an empirical potential structure refinement process.
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Cammarata, L., Kazarian, S. G., Salter, P. A., & Welton, T. (2001) · Physical Chemistry Chemical Physics · doi:10.1039/b106900d · Cited by 1,441
Cited by
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Hayes, R., Warr, G. G., & Atkin, R. (2015) · Chemical Reviews · doi:10.1021/cr500411q · Cited by 2,293
Structural Analysis of Molecular Materials Using the Pair Distribution Function
Terban, M. W., & Billinge, S. J. L. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00237 · Cited by 426
Physico-chemical processes in imidazolium ionic liquids
Dupont, J., & Suarez, P. A. Z. (2006) · Physical Chemistry Chemical Physics · doi:10.1039/b602046a · Cited by 417
Ionic liquids in surface electrochemistry
Liu, H., Liu, Y., & Li, J. (2010) · Physical Chemistry Chemical Physics · doi:10.1039/b921469k · Cited by 372
Metadata
- Authors
- Deetlefs, M., Hardacre, C., Nieuwenhuyzen, M., Sheppard, O., & Soper, A. K.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-11-16
- Volume
- 109
- Issue
- 4
- Pages
- 1593-1598
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W1988425692
- Cited by
- 167
- References
- 1
- FWCI
- 4.29
- Type
- journal article
- Language
- en
- Open access
- closed
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