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Growth of Cu2S Ultrathin Nanowires in a Binary Surfactant Solvent
Abstract
We demonstrate a facile solution-phase method for the synthesis of single-crystal, high aspect ratio, and ultrathin nanowires of hexagonal-phase Cu2S by thermal decomposition of CuS2CNEt2 in a mixed surfactant solvent of dodecanethiol and oleic acid at 160 degrees C. Cu2S nanowires can be controllably synthesized with a diameter as thin as 1.7 nm and length up to tens of micrometers; they are usually aligned in the form of bundles with a thickness of hundreds of nanometers. Based on the experimental results, the formation mechanism of the ultrathin nanowires has been properly proposed. Some key synthetic parameters, which have a significant effect on the sizes and shapes of the products, have also been investigated in detail. UV-vis spectroscopy measurement reveals that the resultant ultrathin nanowires show a strong quantum size effect.
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Cites
Shape control of CdSe nanocrystals
Peng, X., Manna, L., Yang, W., Wickham, J., Scher, E., Kadavanich, A., & Alivisatos, A. P. (2000) · Nature · doi:10.1038/35003535 · Cited by 4,487
Cited by
Gao, M.-R., Xu, Y.-F., Jiang, J., & Yu, S.-H. (2013) · Chemical Society Reviews · doi:10.1039/c2cs35310e · Cited by 1,610
Compound Copper Chalcogenide Nanocrystals
Coughlan, C., Ibáñez, M., Dobrozhan, O., Singh, A., Cabot, A., & Ryan, K. M. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00376 · Cited by 930
A general method for the large-scale synthesis of uniform ultrathin metal sulphide nanocrystals
Du, Y., Yin, Z., Zhu, J., Huang, X., Wu, X.-J., Zeng, Z., Yan, Q., & Zhang, H. (2012) · Nature Communications · doi:10.1038/ncomms2181 · Cited by 414
Lee, H., Yoon, S. W., Kim, E. J., & Park, J. (2007) · Nano Letters · doi:10.1021/nl0630539 · Cited by 337
Gao, M., Jiang, J., & Yu, S. (2012) · Small · doi:10.1002/smll.201101573 · Cited by 289
Metadata
- Authors
- Liu, Z., Xu, D., Liang, J., Shen, J., Zhang, S., & Qian, Y.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-04-30
- Volume
- 109
- Issue
- 21
- Pages
- 10699-10704
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2045109416
- Cited by
- 160
- References
- 1
- FWCI
- 5.24
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liu, Z., Xu, D., Liang, J., Shen, J., Zhang, S., & Qian, Y. (2005). Growth of Cu2S Ultrathin Nanowires in a Binary Surfactant Solvent. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp050332w
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