The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
X-ray Absorption Spectroscopy Study of the Hydrogen Bond Network in the Bulk Water of Aqueous Solutions
Abstract
We utilized X-ray absorption spectroscopy (XAS) and X-ray Raman scattering (XRS) in order to study the ion solvation effect on the bulk hydrogen bonding structure of water. The fine structures in the X-ray absorption spectra are sensitive to the local environment of the probed water molecule related to the hydrogen bond length and angles. By varying the concentration of ions, we can distinguish between contributions from water in the bulk and in the first solvation sphere. We show that the hydrogen bond network in bulk water, in terms of forming and breaking hydrogen bonds as detected by XAS/XRS, remains unchanged, and only the water molecules in the close vicinity to the ions are affected.
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Citations
Cites
Viscosity B-Coefficients of Ions in Solution
Jenkins, H. D. B., & Marcus, Y. (1995) · Chemical Reviews · doi:10.1021/cr00040a004 · Cited by 715
Metadata
- Authors
- Näslund, L.-Å., Edwards, D. C., Wernet, P., Bergmann, U., Ogasawara, H., Pettersson, L. G. M., Myneni, S., & Nilsson, A.
- Venue
- The Journal of Physical Chemistry A
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-06-16
- Volume
- 109
- Issue
- 27
- Pages
- 5995-6002
- ISSN
- 1089-5639 (ISSN-L)
- 1520-5215
- OpenAlex
- W2068030910
- Cited by
- 172
- References
- 1
- FWCI
- 6.56
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
