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Synthesis, Characterization, and Luminescence Properties of the Ternary Europium Complex Covalently Bonded to Mesoporous SBA-15
Abstract
A novel mesoporous SBA-15 type of hybrid material (phen-SBA-15) covalently bonded with 1,10-phenanthroline (phen) ligand was synthesized by co-condensation of tetraethoxysilane (TEOS) and the chelate ligand 5-[N,N-bis-3-(triethoxysilyl)propyl]ureyl-1,10-phenanthroline (phen-Si) in the presence of Pluronic P123 surfactant as a template. The preservation of the chelate ligand structure during the hydrothermal synthesis and the surfactant extraction process was confirmed by Fourier transform infrared (FTIR) and (29)Si MAS NMR spectroscopies. SBA-15 consisting of the highly luminescent ternary complex Eu(TTA)(3)phen (TTA = 2-thenoyltrifluoroacetone) covalently bonded to a silica-based network, which was designated as Eu(TTA)(3)phen-SBA-15, was obtained by introducing the Eu(TTA)(3).2H(2)O complex into the hybrid materials via a ligand exchange reaction. XRD, TEM, and N(2) adsorption measurements were employed to characterize the mesostructure of Eu(TTA)(3)phen-SBA-15. For comparison, SBA-15 doped with Eu(TTA)(3).2H(2)O and Eu(TTA)(3)phen complexes and SBA-15 covalently bonded with a binary europium complex with phen ligand were also synthesized, and were named SBA-15/Eu(TTA)(3), SBA-15/Eu(TTA)(3)phen, and Eu-phen-SBA-15, respectively. The detailed luminescence studies on all the materials showed that, compared with the doping sample SBA-15/Eu(TTA)(3)phen and binary europium complex functionalized sample Eu-phen-SBA-15, the Eu(TTA)(3)phen-SBA-15 mesoporous hybrid material exhibited higher luminescence intensity and emission quantum efficiency. Thermogravimetric analysis on Eu(TTA)(3)phen-SBA-15 demonstrated that the thermal stability of the lanthanide complex was evidently improved as it was covalently bonded to the mesoporous SBA-15 matrix.
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Citations
Cites
Ordered porous materials for emerging applications
Davis, M. E. (2002) · Nature · doi:10.1038/nature00785 · Cited by 5,308
Cited by
Lanthanide-Based Luminescent Hybrid Materials
Binnemans, K. (2009) · Chemical Reviews · doi:10.1021/cr8003983 · Cited by 3,349
pH-Operated Nanopistons on the Surfaces of Mesoporous Silica Nanoparticles
Zhao, Y.-L., Li, Z., Kabehie, S., Botros, Y. Y., Stoddart, J. F., & Zink, J. I. (2010) · Journal of the American Chemical Society · doi:10.1021/ja105371u · Cited by 304
Metadata
- Authors
- Peng, C., Zhang, H., Yu, J., Meng, Q., Fu, L., Li, H., Sun, L., & Guo, X.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-07-23
- Volume
- 109
- Issue
- 32
- Pages
- 15278-15287
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2050644557
- Cited by
- 276
- References
- 1
- FWCI
- 11.49
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Peng, C., Zhang, H., Yu, J., Meng, Q., Fu, L., Li, H., Sun, L., & Guo, X. (2005). Synthesis, Characterization, and Luminescence Properties of the Ternary Europium Complex Covalently Bonded to Mesoporous SBA-15. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp051984n
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