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One-Step Preparation of Single-Crystalline β-MnO2 Nanotubes
Abstract
Single-crystal beta-MnO(2) nanotubes with diameters in the range 200-500 nm and lengths up to several micrometers were successfully prepared by a simple hydrothermal method through oxidizing MnSO(4) with NaClO(3) in the presence of poly(vinyl pyrrolidone) (PVP). It was found that the formation process of beta-MnO(2) nanotubes included two primary evolution stages over time: (1) the MnOOH nanoparticles initially formed in the hydrothermal system and anisotropic growth to nanorods and nanorod aggregates, and (2) the MnOOH nanorods transformed into beta-MnO(2) tubular structure and grown into beta-MnO(2) nanotubes due to continuous growth through a dissolution-recrystallization process eventually. Based on a series of experimental analysis, the formation mechanism of these nanostructures was discussed briefly. The present study has enlarged the family of nanotubes available and offers a possible new, general route to one-dimensional single-crystalline nanotubes of other materials.
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Cites
One‐Dimensional Nanostructures: Synthesis, Characterization, and Applications
Xia, Y., Yang, P., Sun, Y., Wu, Y., Mayers, B., Gates, B., Yin, Y., Kim, F., & Yan, H. (2003) · Advanced Materials · doi:10.1002/adma.200390087 · Cited by 8,559
Shape control of CdSe nanocrystals
Peng, X., Manna, L., Yang, W., Wickham, J., Scher, E., Kadavanich, A., & Alivisatos, A. P. (2000) · Nature · doi:10.1038/35003535 · Cited by 4,487
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Huang, M., Li, F., Dong, F., Zhang, Y. X., & Zhang, L. L. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta05523g · Cited by 929
Quasi-one-dimensional metal oxide materials—Synthesis, properties and applications
Lu, J. G., Chang, P., & Fan, Z. (2006) · Materials Science and Engineering: R: Reports · doi:10.1016/j.mser.2006.04.002 · Cited by 586
Hydrothermal synthetic strategies of inorganic semiconducting nanostructures
Shi, W., Song, S., & Zhang, H. (2013) · Chemical Society Reviews · doi:10.1039/c3cs60012b · Cited by 548
Ding, Y., Xie, J., Cao, G., Zhu, T., Yu, H., & Zhao, X. (2011) · Advanced Functional Materials · doi:10.1002/adfm.201001448 · Cited by 354
Self-citationDevices and chemical sensing applications of metal oxide nanowires
Shen, G., Chen, P.-C., Ryu, K., & Zhou, C. (2009) · J. Mater. Chem. · doi:10.1039/b816543b · Cited by 313
Metadata
- Authors
- Zheng, D., Sun, S., Fan, W., Yu, H., Fan, C., Cao, G., Yin, Z., & Song, X.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-08-06
- Volume
- 109
- Issue
- 34
- Pages
- 16439-16443
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2004410793
- Cited by
- 213
- References
- 2
- FWCI
- 7.66
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zheng, D., Sun, S., Fan, W., Yu, H., Fan, C., Cao, G., Yin, Z., & Song, X. (2005). One-Step Preparation of Single-Crystalline β-MnO2 Nanotubes. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp052370l
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