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Controllable Pt Nanoparticle Deposition on Carbon Nanotubes as an Anode Catalyst for Direct Methanol Fuel Cells
Abstract
We report a novel process to prepare well-dispersed Pt nanoparticles on CNTs. Pt nanoparticles, which were modified by the organic molecule triphenylphosphine, were deposited on multiwalled carbon nanotubes by the organic molecule, which acts as a cross linker. By manipulating the relative ratio of Pt nanoparticles and multiwalled carbon nanotubes in solution, Pt/CNT composites with different Pt content were achieved. The so-prepared Pt/CNT composite materials show higher electrocatalytic activity and better tolerance to poisoning species in methanol oxidation than the commercial E-TEK catalyst, which can be ascribed to the high dispersion of Pt nanoparticles on the multiwalled carbon nanotube surface.
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Cited by
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Han, L., Dong, S., & Wang, E. (2016) · Advanced Materials · doi:10.1002/adma.201602270 · Cited by 1,769
Carbon Nanotube−Inorganic Hybrids
Eder, D. (2010) · Chemical Reviews · doi:10.1021/cr800433k · Cited by 819
Yin, A.-X., Min, X.-Q., Zhang, Y.-W., & Yan, C.-H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja200329p · Cited by 454
Recent advances in Pt-based octahedral nanocrystals as high performance fuel cell catalysts
Wang, J., Li, B., Yersak, T., Yang, D., Xiao, Q., Zhang, J., & Zhang, C. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta02748b · Cited by 65
Nanoparticle seeded pulse electrodeposition for preparing high performance Pt/C electrocatalysts
Huang, C., Bunmi Odetola, C., & Rodgers, M. (2015) · Applied Catalysis A: General · doi:10.1016/j.apcata.2015.03.043 · Cited by 18
Metadata
- Authors
- Mu, Y., Liang, H., Hu, J., Jiang, L., & Wan, L.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-11-02
- Volume
- 109
- Issue
- 47
- Pages
- 22212-22216
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W1992385763
- Cited by
- 474
- References
- 0
- FWCI
- 18.51
- Type
- journal article
- Language
- en
- Open access
- closed
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- Mu, Y., Liang, H., Hu, J., Jiang, L., & Wan, L. (2005). Controllable Pt Nanoparticle Deposition on Carbon Nanotubes as an Anode Catalyst for Direct Methanol Fuel Cells. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp0555448
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
