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Monoclinic Structured BiVO4 Nanosheets: Hydrothermal Preparation, Formation Mechanism, and Coloristic and Photocatalytic Properties

Zhang, Li, Chen, Dairong, Jiao, Xiuling·2006·The Journal of Physical Chemistry B

Abstract

Bismuth vanadate (BiVO(4)) nanosheets have been hydrothermally synthesized in the presence of sodium dodecyl benzene sulfonate (SDBS) as a morphology-directing template. The nanosheets were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) equipped with an X-ray energy dispersive spectrometer (EDS), X-ray photoelectron spectroscopy (XPS), IR spectroscopy, transmission electron microscopy (TEM), and high-resolution TEM (HR-TEM). The BiVO(4) nanosheets had a monoclinic structure, were ca. 10-40 nm thick, and showed a preferred (010) surface orientation. The formation mechanism and the effects of reaction temperature and time on the products were investigated. UV-visible diffuse reflection spectra indicated that the BiVO(4) nanosheets had outstanding spectral selectivity and improved color properties compared with the corresponding bulk materials. Furthermore, the nanosheets showed good visible photocatalytic activities as determined by degradation of N,N,N',N'-tetraethylated rhodamine (RB) under solar irradiation.

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Authors
Zhang, L., Chen, D., & Jiao, X.
Venue
The Journal of Physical Chemistry B
Published
2006-01-26
Volume
110
Issue
6
Pages
2668-2673
ISSN
  • 1520-5207 (ISSN-L)
  • 1520-6106
OpenAlex
W1967082620
Cited by
614
References
0
FWCI
17.91
Type
journal article
Language
en
Open access
closed

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