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Cited by 277

The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.

Structural Effects of Electrochemical Oxidation of Formic Acid on Single Crystal Electrodes of Palladium

Hoshi, Nagahiro, Kida, Kaori, Nakamura, Masashi, Nakada, Miou, Osada, Kazuhito·2006·The Journal of Physical Chemistry B
DOI 10.1021/jp0608372
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Abstract

Structural effects on the rates of formic acid oxidation have been studied on Pd(111), Pd(100), Pd(110), and Pd(S)-[n(100) x (111)] (n = 2-9) electrodes in 0.1 M HClO4 containing 0.1 M formic acid with use of voltammetry. On the low index planes of Pd, the maximum current density of formic acid oxidation (jP) increases in the positive scan as follows: Pd(110) < Pd(111) < Pd(100). This order differs from that on the low index planes of Pt: Pt(111) < Pt(100) < Pt(110). Pd(S)-[n(100) x (111)] electrodes with terrace atomic rows n > or = 3 have almost the same jP as Pd(100), except Pd(911) n = 5. The value of jP on Pd(911) n = 5 is 20% higher than those of the other surfaces. Pd(311) n = 2, of which the first layer is composed of only step atoms, has the lowest jP in the Pd(S)-[n(100) x (111)] series. The adsorption geometry of the reaction intermediate (formate ion) is optimized by using density functional theory.

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Metadata

Authors
Hoshi, N., Kida, K., Nakamura, M., Nakada, M., & Osada, K.
Venue
The Journal of Physical Chemistry B
Publisher
American Chemical Society (ACS)
Published
2006-06-01
Volume
110
Issue
25
Pages
12480-12484
ISSN
  • 1520-5207 (ISSN-L)
  • 1520-6106
DOI
10.1021/jp0608372
OpenAlex
W1982446643
Cited by
277
References
18
FWCI
8.44
Type
journal article
Language
en
Open access
closed

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