The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Influence of a TiCl4Post-Treatment on Nanocrystalline TiO2Films in Dye-Sensitized Solar Cells
Abstract
In this study, the influence of the TiCl(4) post-treatment on nanocrystalline TiO(2) films as electrodes in dye-sensitized solar cells is investigated and compared to nontreated films. As a result of this post-treatment cell efficiencies are improved, due to higher photocurrents. On a microscopic scale TiO(2) particle growth on the order of 1 nm is observed. Despite a corresponding decrease of BET surface area, more dye is adsorbed onto the oxide surface. Although it seems trivial to match this finding with the improved photocurrent, this performance improvement cannot be attributed to higher dye adsorption only. This follows from comparison between incident photon to current conversion efficiency (IPCE) and light absorption characteristics. Since the charge transport properties of the TiO(2) films are already more than sufficient without treatment, the increase in short circuit current density J(SC) cannot be related to improvements in charge transport either. Transient photocurrent measurements indicate a shift in the conduction band edge of the TiO(2) upon TiCl(4) treatment. It is concluded that the main contribution to enhanced current originates from this shift in conduction band edge, resulting in improved charge injection into the TiO(2).
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Citations
Cites
A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films
O'Regan, B., & Grätzel, M. (1991) · Nature · doi:10.1038/353737a0 · Cited by 28,599
Self-citation
Cited by
Liu, B., & Aydil, E. S. (2009) · Journal of the American Chemical Society · doi:10.1021/ja8078972 · Cited by 2,381
Nanostructured photoelectrodes for dye-sensitized solar cells
Zhang, Q., & Cao, G. (2011) · Nano Today · doi:10.1016/j.nantod.2010.12.007 · Cited by 631
Koo, H. ‐., Kim, Y. J., Lee, Y. H., Lee, W. I., Kim, K., & Park, N. ‐. (2008) · Advanced Materials · doi:10.1002/adma.200700840 · Cited by 566
Dye-sensitized solar cells strike back
Muñoz-García, A. B., Benesperi, I., Boschloo, G., Concepcion, J. J., Delcamp, J. H., Gibson, E. A., Meyer, G. J., Pavone, M., Pettersson, H., Hagfeldt, A., et al. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01336f · Cited by 544
O'Regan, B. C., Durrant, J. R., Sommeling, P. M., & Bakker, N. J. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp073056p · Cited by 489
Self-citationBarnes, P. R. F., Miettunen, K., Li, X., Anderson, A. Y., Bessho, T., Gratzel, M., & O'Regan, B. C. (2013) · Advanced Materials · doi:10.1002/adma.201201372 · Cited by 296
Self-citationMetal Oxide Charge Transport Layers for Efficient and Stable Perovskite Solar Cells
Shin, S. S., Lee, S. J., & Seok, S. I. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201900455 · Cited by 283
Metadata
- Authors
- Sommeling, P. M., O'Regan, B. C., Haswell, R. R., Smit, H. J. P., Bakker, N. J., Smits, J. J. T., Kroon, J. M., & van Roosmalen, J. A. M.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-09-08
- Volume
- 110
- Issue
- 39
- Pages
- 19191-19197
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2409079927
- Cited by
- 548
- References
- 1
- FWCI
- 13.05
- Type
- journal article
- Language
- en
- Open access
- closed
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